Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

Rajendra D. Patil; Yoel Sasson

doi:10.1002/ajoc.201500292

Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

Rajendra D. Patil^*, Yoel Sasson

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A non-hazordous and mild protocol was developed for an efficient reduction of alkenes to alkanes using "iron-activated water" and catalytic Pd/C (2.5mol%). Water functions as a hydrogen source without any external acid or base and in the absence of another solvent. The Pd/C catalyst was recovered and recycled. In the course of the reaction zero valent iron is oxidized to magnetite.

Original language	English
Pages (from-to)	1258-1261
Number of pages	4
Journal	Asian Journal of Organic Chemistry
Volume	4
Issue number	11
DOIs	https://doi.org/10.1002/ajoc.201500292
State	Published - Nov 2015

Bibliographical note

Publisher Copyright:
& Co. KGaA, Weinheim.

Keywords

Alkenes
Heterogeneous catalysis
Iron
Magnetite
Transfer hydrogenation
Water

Access to Document

10.1002/ajoc.201500292

Cite this

@article{13f2fb6585834b6caa93a5bcd1aa32ad,

title = "Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C",

abstract = "A non-hazordous and mild protocol was developed for an efficient reduction of alkenes to alkanes using {"}iron-activated water{"} and catalytic Pd/C (2.5mol\%). Water functions as a hydrogen source without any external acid or base and in the absence of another solvent. The Pd/C catalyst was recovered and recycled. In the course of the reaction zero valent iron is oxidized to magnetite.",

keywords = "Alkenes, Heterogeneous catalysis, Iron, Magnetite, Transfer hydrogenation, Water",

author = "Patil, \{Rajendra D.\} and Yoel Sasson",

note = "Publisher Copyright: \& Co. KGaA, Weinheim.",

year = "2015",

month = nov,

doi = "10.1002/ajoc.201500292",

language = "אנגלית",

volume = "4",

pages = "1258--1261",

journal = "Asian Journal of Organic Chemistry",

issn = "2193-5807",

publisher = "John Wiley and Sons Inc.",

number = "11",

}

TY - JOUR

T1 - Generation of Hydrogen from Zero-Valent Iron and Water

T2 - Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

AU - Patil, Rajendra D.

AU - Sasson, Yoel

N1 - Publisher Copyright: & Co. KGaA, Weinheim.

PY - 2015/11

Y1 - 2015/11

N2 - A non-hazordous and mild protocol was developed for an efficient reduction of alkenes to alkanes using "iron-activated water" and catalytic Pd/C (2.5mol%). Water functions as a hydrogen source without any external acid or base and in the absence of another solvent. The Pd/C catalyst was recovered and recycled. In the course of the reaction zero valent iron is oxidized to magnetite.

AB - A non-hazordous and mild protocol was developed for an efficient reduction of alkenes to alkanes using "iron-activated water" and catalytic Pd/C (2.5mol%). Water functions as a hydrogen source without any external acid or base and in the absence of another solvent. The Pd/C catalyst was recovered and recycled. In the course of the reaction zero valent iron is oxidized to magnetite.

KW - Alkenes

KW - Heterogeneous catalysis

KW - Iron

KW - Magnetite

KW - Transfer hydrogenation

KW - Water

UR - https://www.scopus.com/pages/publications/84946485981

U2 - 10.1002/ajoc.201500292

DO - 10.1002/ajoc.201500292

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:84946485981

SN - 2193-5807

VL - 4

SP - 1258

EP - 1261

JO - Asian Journal of Organic Chemistry

JF - Asian Journal of Organic Chemistry

IS - 11

ER -

Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this