Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

Rajendra D. Patil; Yoel Sasson

doi:10.1002/ajoc.201500292

Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

Rajendra D. Patil^*
, Yoel Sasson

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A non-hazordous and mild protocol was developed for an efficient reduction of alkenes to alkanes using "iron-activated water" and catalytic Pd/C (2.5mol%). Water functions as a hydrogen source without any external acid or base and in the absence of another solvent. The Pd/C catalyst was recovered and recycled. In the course of the reaction zero valent iron is oxidized to magnetite.

Original language	English
Pages (from-to)	1258-1261
Number of pages	4
Journal	Asian Journal of Organic Chemistry
Volume	4
Issue number	11
DOIs	https://doi.org/10.1002/ajoc.201500292
State	Published - Nov 2015

Bibliographical note

Publisher Copyright:
& Co. KGaA, Weinheim.

Keywords

Alkenes
Heterogeneous catalysis
Iron
Magnetite
Transfer hydrogenation
Water

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10.1002/ajoc.201500292

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title = "Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C",

abstract = "A non-hazordous and mild protocol was developed for an efficient reduction of alkenes to alkanes using {"}iron-activated water{"} and catalytic Pd/C (2.5mol\%). Water functions as a hydrogen source without any external acid or base and in the absence of another solvent. The Pd/C catalyst was recovered and recycled. In the course of the reaction zero valent iron is oxidized to magnetite.",

keywords = "Alkenes, Heterogeneous catalysis, Iron, Magnetite, Transfer hydrogenation, Water",

author = "Patil, \{Rajendra D.\} and Yoel Sasson",

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year = "2015",

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T2 - Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

AU - Patil, Rajendra D.

AU - Sasson, Yoel

N1 - Publisher Copyright: & Co. KGaA, Weinheim.

PY - 2015/11

Y1 - 2015/11

N2 - A non-hazordous and mild protocol was developed for an efficient reduction of alkenes to alkanes using "iron-activated water" and catalytic Pd/C (2.5mol%). Water functions as a hydrogen source without any external acid or base and in the absence of another solvent. The Pd/C catalyst was recovered and recycled. In the course of the reaction zero valent iron is oxidized to magnetite.

AB - A non-hazordous and mild protocol was developed for an efficient reduction of alkenes to alkanes using "iron-activated water" and catalytic Pd/C (2.5mol%). Water functions as a hydrogen source without any external acid or base and in the absence of another solvent. The Pd/C catalyst was recovered and recycled. In the course of the reaction zero valent iron is oxidized to magnetite.

KW - Alkenes

KW - Heterogeneous catalysis

KW - Iron

KW - Magnetite

KW - Transfer hydrogenation

KW - Water

UR - https://www.scopus.com/pages/publications/84946485981

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DO - 10.1002/ajoc.201500292

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VL - 4

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EP - 1261

JO - Asian Journal of Organic Chemistry

JF - Asian Journal of Organic Chemistry

IS - 11

ER -

Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

Abstract

Bibliographical note

Keywords

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