TY - JOUR
T1 - Gibbs energies of transfer into aqueous alcohols
AU - Marcus, Y.
PY - 1990/1/1
Y1 - 1990/1/1
N2 - Literature data on the standard molar Gibbs energies of transfer of ions X from water W into aqueous alcohol mixtures W+S, [formula omitted] (X,W → W+S)/kJ on the mol L-1 scale at 25.C, are compiled to the end of 1986 and evaluated according to the criteria established in previous parts. The data are presented at evenly spaced mass fractions w of the alcohol in the wixture interpolated where necessary. In the cases of a few ions transferring into aqueous methanol or ethanol ' ‘selected’ values are suggested. Smoothing equations relating [formula omitted] (X, W → W+S) to the mass fraction w of S in the mixture are then presented.
AB - Literature data on the standard molar Gibbs energies of transfer of ions X from water W into aqueous alcohol mixtures W+S, [formula omitted] (X,W → W+S)/kJ on the mol L-1 scale at 25.C, are compiled to the end of 1986 and evaluated according to the criteria established in previous parts. The data are presented at evenly spaced mass fractions w of the alcohol in the wixture interpolated where necessary. In the cases of a few ions transferring into aqueous methanol or ethanol ' ‘selected’ values are suggested. Smoothing equations relating [formula omitted] (X, W → W+S) to the mass fraction w of S in the mixture are then presented.
UR - http://www.scopus.com/inward/record.url?scp=11644308460&partnerID=8YFLogxK
U2 - 10.1351/pac199062050899
DO - 10.1351/pac199062050899
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AN - SCOPUS:11644308460
SN - 0033-4545
VL - 62
SP - 899
EP - 940
JO - Pure and Applied Chemistry
JF - Pure and Applied Chemistry
IS - 5
ER -