Hansen solubility parameters for supercritical water

Yizhak Marcus

doi:10.1016/j.supflu.2011.10.018

Hansen solubility parameters for supercritical water

Yizhak Marcus^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

Expressions are derived for the separate solubility parameters of supercritical water (SCW) due to dispersion, polarity, and hydrogen bonding interactions, in terms of the molar volume of SCW. The molar volumes were calculated from established densities, in turn, and the calculated data are presented as a function of the temperature and the pressure in the ranges relevant to applications of SCW: 400-700 °C and 25-100 MPa.

Original language	English
Pages (from-to)	60-64
Number of pages	5
Journal	Journal of Supercritical Fluids
Volume	62
DOIs	https://doi.org/10.1016/j.supflu.2011.10.018
State	Published - Feb 2012

Keywords

Dispersion
Hansen solubility parameter
Hydrogen bonding
Polarity

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10.1016/j.supflu.2011.10.018

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abstract = "Expressions are derived for the separate solubility parameters of supercritical water (SCW) due to dispersion, polarity, and hydrogen bonding interactions, in terms of the molar volume of SCW. The molar volumes were calculated from established densities, in turn, and the calculated data are presented as a function of the temperature and the pressure in the ranges relevant to applications of SCW: 400-700 °C and 25-100 MPa.",

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AB - Expressions are derived for the separate solubility parameters of supercritical water (SCW) due to dispersion, polarity, and hydrogen bonding interactions, in terms of the molar volume of SCW. The molar volumes were calculated from established densities, in turn, and the calculated data are presented as a function of the temperature and the pressure in the ranges relevant to applications of SCW: 400-700 °C and 25-100 MPa.

KW - Dispersion

KW - Hansen solubility parameter

KW - Hydrogen bonding

KW - Polarity

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JO - Journal of Supercritical Fluids

JF - Journal of Supercritical Fluids

ER -

Hansen solubility parameters for supercritical water

Abstract

Keywords

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