High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*Movtrinuclear cation by chemical reduction of Cp*2Mo2O5

Funda Demirhan; Jenny Gun; Ovadia Lev; Alexandre Modestov; Rinaldo Poli; Philippe Richard

doi:10.1039/b203583a

High oxidation state aqueous organometallics. Formation and structure of an oxo-centred CpMo^vtrinuclear cation by chemical reduction of Cp₂Mo₂O₅

Funda Demirhan, Jenny Gun, Ovadia Lev, Alexandre Modestov, Rinaldo Poli, Philippe Richard

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Abstract

Reduction of Cp*₂Mo₂O₅by zinc/CF₃CO₂H in MeOH-H₂O yields a salt which is composed of [Cp*₃Mo₃O₄(O₂CCF ₃)₃]⁺and [Zn₂(O₂CCF₃)₆]²ions after crystallisation from THF-Et₂O.

Original language	English
Pages (from-to)	2109-2111
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/b203583a
State	Published - 2002
Externally published	Yes

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title = "High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*Movtrinuclear cation by chemical reduction of Cp*2Mo2O5",

abstract = "Reduction of Cp*2Mo2O5by zinc/CF3CO2H in MeOH-H2O yields a salt which is composed of [Cp*3Mo3O4(O2CCF 3)3]+and [Zn2(O2CCF3)6]2ions after crystallisation from THF-Et2O.",

author = "Funda Demirhan and Jenny Gun and Ovadia Lev and Alexandre Modestov and Rinaldo Poli and Philippe Richard",

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doi = "10.1039/b203583a",

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T1 - High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*Movtrinuclear cation by chemical reduction of Cp*2Mo2O5

AU - Demirhan, Funda

AU - Gun, Jenny

AU - Lev, Ovadia

AU - Modestov, Alexandre

AU - Poli, Rinaldo

AU - Richard, Philippe

PY - 2002

Y1 - 2002

N2 - Reduction of Cp*2Mo2O5by zinc/CF3CO2H in MeOH-H2O yields a salt which is composed of [Cp*3Mo3O4(O2CCF 3)3]+and [Zn2(O2CCF3)6]2ions after crystallisation from THF-Et2O.

AB - Reduction of Cp*2Mo2O5by zinc/CF3CO2H in MeOH-H2O yields a salt which is composed of [Cp*3Mo3O4(O2CCF 3)3]+and [Zn2(O2CCF3)6]2ions after crystallisation from THF-Et2O.

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JO - Journal of the Chemical Society. Dalton Transactions

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High oxidation state aqueous organometallics. Formation and structure of an oxo-centred CpMo^vtrinuclear cation by chemical reduction of Cp₂Mo₂O₅

Abstract

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