Highly charged cellulose nanocrystals applied as a water treatment flocculant

Dana Morantes, Efrén Muñoz, Doron Kam, Oded Shoseyov*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

47 Scopus citations

Abstract

Various cellulosic materials have replaced petroleum-derived polymers, offering natural and sustainable alternatives. Among them, cellulose nanocrystals (CNC) feature an easily modifiable surface, enabling the exploration of a wide spectrum of applications. In this work, the quaternary agent 3-chloro-2-hydroxypropyltrimethylammonium chloride (CHPTAC) was used as a cationic graft on CNCs, to form a novel water treatment flocculant. The resulting material was chemically and structurally characterized by the determination of Zeta potential; degree of substitution by elemental analysis; hydrodynamic size by dynamic light scattering (DLS) and infrared spectroscopy with Fourier Transform Infrared (FT-IR); and X-ray diffraction (XRD). The flocculation capacity of cationic cellulose nanocrystals (CNC-EPTMAC) was evaluated in a jar test filled with an 0.25 wt.% silica (SiO2) suspension. CNC-EPTMAC proved to be an effective water treatment flocculant, reducing turbidity by up to 99.7% at a concentration of only 2 ppm. This work demonstrates a natural and environmentally sustainable alternative to homologous commercial flocculants.

Original languageAmerican English
Article number272
JournalNanomaterials
Volume9
Issue number2
DOIs
StatePublished - Feb 2019

Bibliographical note

Publisher Copyright:
© 2019 by the authors. Licensee MDPI, Basel, Switzerland.

Keywords

  • Flocculation
  • Nanocellulose
  • Quaternary agent
  • Surface modification

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