Homogeneous Decarbonylation of Formate Esters Catalyzed by Vaska's Compound

Hayder A. Zahalka; Howard Alper; Yoei Sasson

doi:10.1021/om00143a015

Homogeneous Decarbonylation of Formate Esters Catalyzed by Vaska's Compound

Hayder A. Zahalka, Howard Alper, Yoei Sasson

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

Vaska's compound, chlorocarbonylbis(triphenylphosphine)iridium(I), can catalyze the decarbonylation of formate esters to alcohols and carbon monoxide. The reaction proceeds at atmospheric pressure and at 160–240 °C, depending on the reaction conditions (i.e., solvent, open vs. closed system).

Original language	English
Pages (from-to)	2497-2499
Number of pages	3
Journal	Organometallics
Volume	5
Issue number	12
DOIs	https://doi.org/10.1021/om00143a015
State	Published - 1986

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title = "Homogeneous Decarbonylation of Formate Esters Catalyzed by Vaska's Compound",

abstract = "Vaska's compound, chlorocarbonylbis(triphenylphosphine)iridium(I), can catalyze the decarbonylation of formate esters to alcohols and carbon monoxide. The reaction proceeds at atmospheric pressure and at 160–240 °C, depending on the reaction conditions (i.e., solvent, open vs. closed system).",

author = "Zahalka, \{Hayder A.\} and Howard Alper and Yoei Sasson",

year = "1986",

doi = "10.1021/om00143a015",

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journal = "Organometallics",

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T1 - Homogeneous Decarbonylation of Formate Esters Catalyzed by Vaska's Compound

AU - Zahalka, Hayder A.

AU - Alper, Howard

AU - Sasson, Yoei

PY - 1986

Y1 - 1986

N2 - Vaska's compound, chlorocarbonylbis(triphenylphosphine)iridium(I), can catalyze the decarbonylation of formate esters to alcohols and carbon monoxide. The reaction proceeds at atmospheric pressure and at 160–240 °C, depending on the reaction conditions (i.e., solvent, open vs. closed system).

AB - Vaska's compound, chlorocarbonylbis(triphenylphosphine)iridium(I), can catalyze the decarbonylation of formate esters to alcohols and carbon monoxide. The reaction proceeds at atmospheric pressure and at 160–240 °C, depending on the reaction conditions (i.e., solvent, open vs. closed system).

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AN - SCOPUS:0038261302

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SP - 2497

EP - 2499

JO - Organometallics

JF - Organometallics

IS - 12

ER -

Homogeneous Decarbonylation of Formate Esters Catalyzed by Vaska's Compound

Abstract

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