Homogeneous vs. heterogeneous processes in electrocatalysis. Different types of catalysis in organic electrooxidation

M. Michman

doi:10.1016/1381-1169(95)00238-3

Homogeneous vs. heterogeneous processes in electrocatalysis. Different types of catalysis in organic electrooxidation

M. Michman^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Electrochemical reactions involve surface-solution interface that may display properties relevant to homogeneous and heterogeneous catalysis. Examples are taken from the catalysis by RuCl₃ and Ru(acac)₃ of the accelerated electrooxidation of water when it is linked with oxidation of naphthalene, 2-methylnaphthalene and some aryl ethers. The influence of tetrabutylammonium dichromate and of diisobutylamine on the electrochemical reaction is discussed in terms of interface effects on the diffuse layer and selectivity to naphthoquinone, and 2-methylnaphthoquinone as products.

Original language	English
Pages (from-to)	393-398
Number of pages	6
Journal	Journal of Molecular Catalysis A: Chemical
Volume	107
Issue number	1-3
DOIs	https://doi.org/10.1016/1381-1169(95)00238-3
State	Published - 1996

Keywords

2-Methylnaphthalene
2-Methylnaphthoquinone
Diffuse layer
Diisobutylamine
Electrochemistry
Electrooxidation
Heterogeneous catalysis
Homogeneous catalysis
Oxidation
Ru(acac)
RuCl
Tetrabutylammonium dichromate

Access to Document

10.1016/1381-1169(95)00238-3

Cite this

@article{0258ed19a20f4efe9db2acbc5f9ed8ac,

title = "Homogeneous vs. heterogeneous processes in electrocatalysis. Different types of catalysis in organic electrooxidation",

abstract = "Electrochemical reactions involve surface-solution interface that may display properties relevant to homogeneous and heterogeneous catalysis. Examples are taken from the catalysis by RuCl3 and Ru(acac)3 of the accelerated electrooxidation of water when it is linked with oxidation of naphthalene, 2-methylnaphthalene and some aryl ethers. The influence of tetrabutylammonium dichromate and of diisobutylamine on the electrochemical reaction is discussed in terms of interface effects on the diffuse layer and selectivity to naphthoquinone, and 2-methylnaphthoquinone as products.",

keywords = "2-Methylnaphthalene, 2-Methylnaphthoquinone, Diffuse layer, Diisobutylamine, Electrochemistry, Electrooxidation, Heterogeneous catalysis, Homogeneous catalysis, Oxidation, Ru(acac), RuCl, Tetrabutylammonium dichromate",

author = "M. Michman",

year = "1996",

doi = "10.1016/1381-1169(95)00238-3",

language = "אנגלית",

volume = "107",

pages = "393--398",

journal = "Journal of Molecular Catalysis A: Chemical",

issn = "1381-1169",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Homogeneous vs. heterogeneous processes in electrocatalysis. Different types of catalysis in organic electrooxidation

AU - Michman, M.

PY - 1996

Y1 - 1996

N2 - Electrochemical reactions involve surface-solution interface that may display properties relevant to homogeneous and heterogeneous catalysis. Examples are taken from the catalysis by RuCl3 and Ru(acac)3 of the accelerated electrooxidation of water when it is linked with oxidation of naphthalene, 2-methylnaphthalene and some aryl ethers. The influence of tetrabutylammonium dichromate and of diisobutylamine on the electrochemical reaction is discussed in terms of interface effects on the diffuse layer and selectivity to naphthoquinone, and 2-methylnaphthoquinone as products.

AB - Electrochemical reactions involve surface-solution interface that may display properties relevant to homogeneous and heterogeneous catalysis. Examples are taken from the catalysis by RuCl3 and Ru(acac)3 of the accelerated electrooxidation of water when it is linked with oxidation of naphthalene, 2-methylnaphthalene and some aryl ethers. The influence of tetrabutylammonium dichromate and of diisobutylamine on the electrochemical reaction is discussed in terms of interface effects on the diffuse layer and selectivity to naphthoquinone, and 2-methylnaphthoquinone as products.

KW - 2-Methylnaphthalene

KW - 2-Methylnaphthoquinone

KW - Diffuse layer

KW - Diisobutylamine

KW - Electrochemistry

KW - Electrooxidation

KW - Heterogeneous catalysis

KW - Homogeneous catalysis

KW - Oxidation

KW - Ru(acac)

KW - RuCl

KW - Tetrabutylammonium dichromate

UR - http://www.scopus.com/inward/record.url?scp=0030572075&partnerID=8YFLogxK

U2 - 10.1016/1381-1169(95)00238-3

DO - 10.1016/1381-1169(95)00238-3

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0030572075

SN - 1381-1169

VL - 107

SP - 393

EP - 398

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-3

ER -

Homogeneous vs. heterogeneous processes in electrocatalysis. Different types of catalysis in organic electrooxidation

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this