Hybrid Silsesquioxane/Benzoate Cu₇-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity

Keyphrases

• Catalytic Activity 100%
• Cage Structure 100%
• Structure-activity 100%
• Benzoate 100%
• Complex Synthesis 100%
• Silsesquioxane 100%
• Cyclohexanol 66%
• Benzyl Alcohol 66%
• Cyclohexyl Hydroperoxide 66%
• Ligation 33%
• Pyridine 33%
• Toluene 33%
• High Activity 33%
• Hydrogen Peroxide 33%
• Solvate 33%
• Tert-butyl Hydroperoxide (t-BHP) 33%
• Structural Features 33%
• X-ray Crystallography 33%
• Acetonitrile 33%
• Regioselectivity 33%
• Directed Self-assembly 33%
• Ketones 33%
• Benzoic Acid 33%
• Triphenylphosphine 33%
• Oxidation Products 33%
• Heptane 33%
• Regio 33%
• Chemoselectivity 33%
• Maximum Yield 33%
• Spontaneous Oxidation 33%
• Dimethylformamide 33%
• Cyclohexanone 33%
• Oxidation Reaction 33%
• Alcohol Oxidation 33%
• Benzyl Benzoate 33%
• Methylcyclohexane 33%
• Phenylsilsesquioxane 33%
• Benzoate Ligand 33%
• Cyclohexane Oxidation 33%
• Alkyl Alcohol 33%
• Heptanuclear 33%
• Alkyl Hydroperoxides 33%
• Alkane Oxidation 33%
• Copper Ion 33%
• Hydroxyl Radical ([rad]OH) 33%

Chemistry

• Benzoate 100%
• Silsesquioxane 100%
• Catalyst Activity 100%
• Hydroperoxide 50%
• Cyclohexanol 50%
• Benzyl Alcohol 50%
• Chemoselectivity 25%
• X-Ray Crystallography 25%
• Hydrogen Peroxide 25%
• Oxidation Reaction 25%
• Ketones 25%
• Hydroxyl Radical 25%
• Acetonitrile 25%
• Cyclohexane 25%
• Regioselectivity 25%
• Triphenylphosphine 25%
• Benzoic Acid 25%
• Formamide 25%
• Tert-Butyl Hydroperoxide 25%
• Alkyl Hydroperoxide 25%
• Cyclohexanone 25%
• Alkyl Alcohol 25%
• Benzyl Benzoate 25%
• formation 25%
• solvate 25%
• oxidation of alkanes 25%
• Catalyst 25%
• Pyridine 25%
• Toluene 25%