TY - JOUR
T1 - Hydrophobic interaction in light and heavy water
AU - Ben-Naim, A.
AU - Wilf, J.
AU - Yaacobi, M.
PY - 1973
Y1 - 1973
N2 - The solubility, free energy, entropy, and enthalpy of solution of methane, ethane, n-butane, benzene, and biphenyl were determined in light and heavy water. The hydrophobic interaction between the pairs methane-methane, ethane-ethane, and benzene-benzene were computed in these two liquids. It was found that the strength of the hydrophobic interaction for the first two pairs is larger in H2O than in D2O. The order seems to be reversed for the pair benzene-benzene.
AB - The solubility, free energy, entropy, and enthalpy of solution of methane, ethane, n-butane, benzene, and biphenyl were determined in light and heavy water. The hydrophobic interaction between the pairs methane-methane, ethane-ethane, and benzene-benzene were computed in these two liquids. It was found that the strength of the hydrophobic interaction for the first two pairs is larger in H2O than in D2O. The order seems to be reversed for the pair benzene-benzene.
UR - http://www.scopus.com/inward/record.url?scp=33947087505&partnerID=8YFLogxK
U2 - 10.1021/j100620a021
DO - 10.1021/j100620a021
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AN - SCOPUS:33947087505
SN - 0022-3654
VL - 77
SP - 95
EP - 102
JO - Journal of Physical Chemistry
JF - Journal of Physical Chemistry
IS - 1
ER -