Hydroxide ion initiated reactions under phase transfer catalysis conditions-IV. Effect of catalyst structure

Marc Halpern; Yoel Sasson; Mordecai Rabinovitz

doi:10.1016/0040-4020(82)80057-4

Hydroxide ion initiated reactions under phase transfer catalysis conditions-IV. Effect of catalyst structure

Marc Halpern^*
, Yoel Sasson
, Mordecai Rabinovitz

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

The nature of the quat-anion interactions in a PTC/OH^- system was probed by examining the reactivity and selectivity of a CA/O-ambident anion towards an alkylating agent in the presence of various quats. It is suggested that the accessibility of the positive N center of the qual for association with the anion is the major factor in determining the behavior of PTC/OH^- reactions proceeding through the Makosza mechanism.

Original language	English
Pages (from-to)	3183-3187
Number of pages	5
Journal	Tetrahedron
Volume	38
Issue number	21
DOIs	https://doi.org/10.1016/0040-4020(82)80057-4
State	Published - 1982

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title = "Hydroxide ion initiated reactions under phase transfer catalysis conditions-IV. Effect of catalyst structure",

abstract = "The nature of the quat-anion interactions in a PTC/OH- system was probed by examining the reactivity and selectivity of a CA/O-ambident anion towards an alkylating agent in the presence of various quats. It is suggested that the accessibility of the positive N center of the qual for association with the anion is the major factor in determining the behavior of PTC/OH- reactions proceeding through the Makosza mechanism.",

author = "Marc Halpern and Yoel Sasson and Mordecai Rabinovitz",

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AU - Sasson, Yoel

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N2 - The nature of the quat-anion interactions in a PTC/OH- system was probed by examining the reactivity and selectivity of a CA/O-ambident anion towards an alkylating agent in the presence of various quats. It is suggested that the accessibility of the positive N center of the qual for association with the anion is the major factor in determining the behavior of PTC/OH- reactions proceeding through the Makosza mechanism.

AB - The nature of the quat-anion interactions in a PTC/OH- system was probed by examining the reactivity and selectivity of a CA/O-ambident anion towards an alkylating agent in the presence of various quats. It is suggested that the accessibility of the positive N center of the qual for association with the anion is the major factor in determining the behavior of PTC/OH- reactions proceeding through the Makosza mechanism.

UR - https://www.scopus.com/pages/publications/0000901570

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JO - Tetrahedron

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Hydroxide ion initiated reactions under phase transfer catalysis conditions-IV. Effect of catalyst structure

Abstract

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