Hydroxide Ion Initiated Reactions under Phase-Transfer-Catalysis Conditions. 5. Isomerization of Allylbenzene via Hydroxide Ion Extraction

Marc Halpern; Yoel Sasson; Mordecai Rabinovitz

doi:10.1021/jo00155a018

Hydroxide Ion Initiated Reactions under Phase-Transfer-Catalysis Conditions. 5. Isomerization of Allylbenzene via Hydroxide Ion Extraction

Marc Halpern
, Yoel Sasson
, Mordecai Rabinovitz

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

88 Scopus citations

Abstract

Kinetic data are reported regarding the isomerization of allylbenzene under phase-transfer-catalysis (PTC/OH^-) conditions. The dependency of these data on the stirring rate, catalyst structure, catalyst concentration, temperature, counterion, and aqueous hydroxide ion concentration are consistent with a hydroxide ion extraction mechanism.

Original language	English
Pages (from-to)	1022-1025
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	48
Issue number	7
DOIs	https://doi.org/10.1021/jo00155a018
State	Published - Apr 1983

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title = "Hydroxide Ion Initiated Reactions under Phase-Transfer-Catalysis Conditions. 5. Isomerization of Allylbenzene via Hydroxide Ion Extraction",

abstract = "Kinetic data are reported regarding the isomerization of allylbenzene under phase-transfer-catalysis (PTC/OH-) conditions. The dependency of these data on the stirring rate, catalyst structure, catalyst concentration, temperature, counterion, and aqueous hydroxide ion concentration are consistent with a hydroxide ion extraction mechanism.",

author = "Marc Halpern and Yoel Sasson and Mordecai Rabinovitz",

year = "1983",

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AU - Sasson, Yoel

AU - Rabinovitz, Mordecai

PY - 1983/4

Y1 - 1983/4

N2 - Kinetic data are reported regarding the isomerization of allylbenzene under phase-transfer-catalysis (PTC/OH-) conditions. The dependency of these data on the stirring rate, catalyst structure, catalyst concentration, temperature, counterion, and aqueous hydroxide ion concentration are consistent with a hydroxide ion extraction mechanism.

AB - Kinetic data are reported regarding the isomerization of allylbenzene under phase-transfer-catalysis (PTC/OH-) conditions. The dependency of these data on the stirring rate, catalyst structure, catalyst concentration, temperature, counterion, and aqueous hydroxide ion concentration are consistent with a hydroxide ion extraction mechanism.

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Hydroxide Ion Initiated Reactions under Phase-Transfer-Catalysis Conditions. 5. Isomerization of Allylbenzene via Hydroxide Ion Extraction

Abstract

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