Hydroxylation of Alkanes with Molecular Oxygen Catalyzed by a New Ruthenium‐Substituted Polyoxometalate, [WZnRu 2III(OH)(H2O)(ZnW9O34)2]11−

Ronny Neumann; Alexander M. Khenkin; Mazal Dahan

doi:10.1002/anie.199515871

Hydroxylation of Alkanes with Molecular Oxygen Catalyzed by a New Ruthenium‐Substituted Polyoxometalate, [WZnRu 2III(OH)(H₂O)(ZnW₉O₃₄)₂]¹¹⁻

Ronny Neumann^*, Alexander M. Khenkin, Mazal Dahan

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

96 Scopus citations

Abstract

Highly selective aerobic hydroxylation of tertiary carbon centers in alkanes is catalyzed by the title polyoxometalate under mild reaction conditions [Eq. (a)]. This is of great significance, in particular in the search for ways to activate molecular oxygen in the oxidation of hydrocarbons. (Figure Presented.)

Original language	English
Pages (from-to)	1587-1589
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	34
Issue number	15
DOIs	https://doi.org/10.1002/anie.199515871
State	Published - 18 Aug 1995

Keywords

oxygen activation
polyoxometalates
ruthenium compounds

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10.1002/anie.199515871

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abstract = "Highly selective aerobic hydroxylation of tertiary carbon centers in alkanes is catalyzed by the title polyoxometalate under mild reaction conditions [Eq. (a)]. This is of great significance, in particular in the search for ways to activate molecular oxygen in the oxidation of hydrocarbons. (Figure Presented.)",

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year = "1995",

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AU - Khenkin, Alexander M.

AU - Dahan, Mazal

PY - 1995/8/18

Y1 - 1995/8/18

N2 - Highly selective aerobic hydroxylation of tertiary carbon centers in alkanes is catalyzed by the title polyoxometalate under mild reaction conditions [Eq. (a)]. This is of great significance, in particular in the search for ways to activate molecular oxygen in the oxidation of hydrocarbons. (Figure Presented.)

AB - Highly selective aerobic hydroxylation of tertiary carbon centers in alkanes is catalyzed by the title polyoxometalate under mild reaction conditions [Eq. (a)]. This is of great significance, in particular in the search for ways to activate molecular oxygen in the oxidation of hydrocarbons. (Figure Presented.)

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Hydroxylation of Alkanes with Molecular Oxygen Catalyzed by a New Ruthenium‐Substituted Polyoxometalate, [WZnRu 2III(OH)(H₂O)(ZnW₉O₃₄)₂]¹¹⁻

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Keywords

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