In situ EPR study of sol-gel processes

A. Shames; O. Lev; B. Iosefzon-Kuyavskaya

doi:10.1016/0022-3093(94)90310-7

In situ EPR study of sol-gel processes

A. Shames^*, O. Lev, B. Iosefzon-Kuyavskaya

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The electron paramagnetic resonance (EPR) spectra of the stable free radical (4-oxo-Tempo) were investigated during sol-gel-xerogel transition both for non-doped and o-phenanthroline-doped silica glasses. Gradual changes in linewidths, rotation correlation time, isotropic hyperfine interaction parameters and integral line intensities were observed. These spectral changes reflect variations in the composition, effective viscosity and polarity of the cage media in the vicinity of the probe. The EPR spectroscopy of stable free radicals as paramagnetic probes is demonstrated to provide a non-intrunsive in situ means to monitor structural and chemical changes during sol-gel glass formation.

Original language	English
Pages (from-to)	14-20
Number of pages	7
Journal	Journal of Non-Crystalline Solids
Volume	175
Issue number	1
DOIs	https://doi.org/10.1016/0022-3093(94)90310-7
State	Published - 2 Sep 1994

Bibliographical note

Funding Information:
The authors would like to thank Dr E.M. Kunoff (BGU) for helpful discussions and friendly support in the manuscript preparation. This research was supported by grants from the Ministry of Immigrant Absorption and Ministry of Science and Technology (Israel), and Forschungszentrum fur Umwelt und Gesundheit GmbH, Neuerberg (Germany).

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title = "In situ EPR study of sol-gel processes",

abstract = "The electron paramagnetic resonance (EPR) spectra of the stable free radical (4-oxo-Tempo) were investigated during sol-gel-xerogel transition both for non-doped and o-phenanthroline-doped silica glasses. Gradual changes in linewidths, rotation correlation time, isotropic hyperfine interaction parameters and integral line intensities were observed. These spectral changes reflect variations in the composition, effective viscosity and polarity of the cage media in the vicinity of the probe. The EPR spectroscopy of stable free radicals as paramagnetic probes is demonstrated to provide a non-intrunsive in situ means to monitor structural and chemical changes during sol-gel glass formation.",

author = "A. Shames and O. Lev and B. Iosefzon-Kuyavskaya",

note = "Funding Information: The authors would like to thank Dr E.M. Kunoff (BGU) for helpful discussions and friendly support in the manuscript preparation. This research was supported by grants from the Ministry of Immigrant Absorption and Ministry of Science and Technology (Israel), and Forschungszentrum fur Umwelt und Gesundheit GmbH, Neuerberg (Germany).",

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N2 - The electron paramagnetic resonance (EPR) spectra of the stable free radical (4-oxo-Tempo) were investigated during sol-gel-xerogel transition both for non-doped and o-phenanthroline-doped silica glasses. Gradual changes in linewidths, rotation correlation time, isotropic hyperfine interaction parameters and integral line intensities were observed. These spectral changes reflect variations in the composition, effective viscosity and polarity of the cage media in the vicinity of the probe. The EPR spectroscopy of stable free radicals as paramagnetic probes is demonstrated to provide a non-intrunsive in situ means to monitor structural and chemical changes during sol-gel glass formation.

AB - The electron paramagnetic resonance (EPR) spectra of the stable free radical (4-oxo-Tempo) were investigated during sol-gel-xerogel transition both for non-doped and o-phenanthroline-doped silica glasses. Gradual changes in linewidths, rotation correlation time, isotropic hyperfine interaction parameters and integral line intensities were observed. These spectral changes reflect variations in the composition, effective viscosity and polarity of the cage media in the vicinity of the probe. The EPR spectroscopy of stable free radicals as paramagnetic probes is demonstrated to provide a non-intrunsive in situ means to monitor structural and chemical changes during sol-gel glass formation.

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In situ EPR study of sol-gel processes

Abstract

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