TY - JOUR
T1 - Induction of Crystallization of Specific Calcium Oxalate Hydrates in Micellar Solutions of Surfactants
AU - Füredi-Milhofer, H.
AU - Bloch, R.
AU - Garti, N.
AU - Skrtic, D.
AU - Füredi-Milhofer, H.
AU - Filipovic-Vincekovic, N.
PY - 1993
Y1 - 1993
N2 - The influence of octaethylene glycol mono-n-hexadecyl ether (C16EO8) and sodium dodecyl sulphate (SDS) on the crystallization of calcium oxalate from 0.3 mol dm-3 sodium chloride solutions has been investigated. The critical micellar concentration (CMC) of C16EO8 in water and 0.3 mol dm-3 NaCl was determined by surface tension measurements (CMCH2O=CMCNaCl = 7.2.10-6 mol dm-3). The kinetics of precipitation of calcium oxalate was followed by Coulter counter, and solid phases were characterized by polarized microscopy, thermal analysis and X-ray powder diffraction patterns. Under the precipitation conditions employed, the thermodynamically stable monohydrate, CaC2O4•H2O (COM) was the predominant crystalline form. In the presence of micellar solutions of C16EO8 precipitation of this phase was facilitated as evidenced by higher initial precipitation rates and higher precipitate volume and number of particles, as compared to the controls. Micellar solutions of SDS retarded precipitation but induced crystallization of calcium oxalate dihydrate, CaC2O4•(2+x)H2O (COD, x≤0.5). Thus at c(SDS)>CMC the precipitates contained ≤85 mass % COD. The results are discussed in relation to previously reported data on the precipitation of calcium oxalate in the presence of dodecyl ammonium chloride.
AB - The influence of octaethylene glycol mono-n-hexadecyl ether (C16EO8) and sodium dodecyl sulphate (SDS) on the crystallization of calcium oxalate from 0.3 mol dm-3 sodium chloride solutions has been investigated. The critical micellar concentration (CMC) of C16EO8 in water and 0.3 mol dm-3 NaCl was determined by surface tension measurements (CMCH2O=CMCNaCl = 7.2.10-6 mol dm-3). The kinetics of precipitation of calcium oxalate was followed by Coulter counter, and solid phases were characterized by polarized microscopy, thermal analysis and X-ray powder diffraction patterns. Under the precipitation conditions employed, the thermodynamically stable monohydrate, CaC2O4•H2O (COM) was the predominant crystalline form. In the presence of micellar solutions of C16EO8 precipitation of this phase was facilitated as evidenced by higher initial precipitation rates and higher precipitate volume and number of particles, as compared to the controls. Micellar solutions of SDS retarded precipitation but induced crystallization of calcium oxalate dihydrate, CaC2O4•(2+x)H2O (COD, x≤0.5). Thus at c(SDS)>CMC the precipitates contained ≤85 mass % COD. The results are discussed in relation to previously reported data on the precipitation of calcium oxalate in the presence of dodecyl ammonium chloride.
UR - http://www.scopus.com/inward/record.url?scp=0027151114&partnerID=8YFLogxK
U2 - 10.1080/01932699308943408
DO - 10.1080/01932699308943408
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AN - SCOPUS:0027151114
SN - 0193-2691
VL - 14
SP - 355
EP - 371
JO - Journal of Dispersion Science and Technology
JF - Journal of Dispersion Science and Technology
IS - 3
ER -