Infrared Study of the Adsorption of Benzoic Acid and Nitrobenzene in Montmorillonite

S. Yariv; J. D. Russell; V. C. Farmer

doi:10.1002/ijch.196600034

Infrared Study of the Adsorption of Benzoic Acid and Nitrobenzene in Montmorillonite

S. Yariv^*
, J. D. Russell
, V. C. Farmer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

Nitrobenzene and benzoic acid are coordinated through water molecules to the more highly polarizing exchangeable cations in the interlayer space of montmorillonite, but are directly coordinated to NH₄⁺ and possibly also K⁺: On dehydration of the adsorption complexes the nitrobenzene and benzoic acid become directly coordinated to all of the exchangeable cations investigated. Benzoate ion was also formed in amounts which were dependent on the exchangeable cations.

Original language	English
Pages (from-to)	201-213
Number of pages	13
Journal	Israel Journal of Chemistry
Volume	4
Issue number	5-6
DOIs	https://doi.org/10.1002/ijch.196600034
State	Published - 1966
Externally published	Yes

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title = "Infrared Study of the Adsorption of Benzoic Acid and Nitrobenzene in Montmorillonite",

abstract = "Nitrobenzene and benzoic acid are coordinated through water molecules to the more highly polarizing exchangeable cations in the interlayer space of montmorillonite, but are directly coordinated to NH4+ and possibly also K+: On dehydration of the adsorption complexes the nitrobenzene and benzoic acid become directly coordinated to all of the exchangeable cations investigated. Benzoate ion was also formed in amounts which were dependent on the exchangeable cations.",

author = "S. Yariv and Russell, \{J. D.\} and Farmer, \{V. C.\}",

year = "1966",

doi = "10.1002/ijch.196600034",

language = "אנגלית",

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issn = "0021-2148",

publisher = "Wiley-Blackwell",

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AU - Yariv, S.

AU - Russell, J. D.

AU - Farmer, V. C.

PY - 1966

Y1 - 1966

N2 - Nitrobenzene and benzoic acid are coordinated through water molecules to the more highly polarizing exchangeable cations in the interlayer space of montmorillonite, but are directly coordinated to NH4+ and possibly also K+: On dehydration of the adsorption complexes the nitrobenzene and benzoic acid become directly coordinated to all of the exchangeable cations investigated. Benzoate ion was also formed in amounts which were dependent on the exchangeable cations.

AB - Nitrobenzene and benzoic acid are coordinated through water molecules to the more highly polarizing exchangeable cations in the interlayer space of montmorillonite, but are directly coordinated to NH4+ and possibly also K+: On dehydration of the adsorption complexes the nitrobenzene and benzoic acid become directly coordinated to all of the exchangeable cations investigated. Benzoate ion was also formed in amounts which were dependent on the exchangeable cations.

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DO - 10.1002/ijch.196600034

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AN - SCOPUS:84989991712

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JO - Israel Journal of Chemistry

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ER -

Infrared Study of the Adsorption of Benzoic Acid and Nitrobenzene in Montmorillonite

Abstract

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