Intermolecular vibrational motion in CS2 liquid at 165 ≤ T≥ 300 K observed by femtosecond time-resolved impulsive stimulated scattering

S. Ruhman; Bern Kohler; Alan G. Joly; Keith A. Nelson

doi:10.1016/0009-2614(87)80084-2

Intermolecular vibrational motion in CS₂ liquid at 165 ≤ T≥ 300 K observed by femtosecond time-resolved impulsive stimulated scattering

S. Ruhman^*
, Bern Kohler
, Alan G. Joly
, Keith A. Nelson

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

82 Scopus citations

Abstract

Temperature-dependent molecular dynamics of CS₂ liquid are examined in femtosecond time-resolved impulsive stimulated scattering experiments. At temperatures T≤ 240 K, weakly oscillatory time-dependent responses are observed. These are interpreted in terms of librations of molecules about their local potential minima. The librations undergo rapid inhomogeneous dephasing. Temperature-dependent values of the configuration-averaged librational frequency and the extent of inhomogeneity in that frequency are determined.

Original language	English
Pages (from-to)	16-24
Number of pages	9
Journal	Chemical Physics Letters
Volume	141
Issue number	1-2
DOIs	https://doi.org/10.1016/0009-2614(87)80084-2
State	Published - 30 Oct 1987
Externally published	Yes

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title = "Intermolecular vibrational motion in CS2 liquid at 165 ≤ T≥ 300 K observed by femtosecond time-resolved impulsive stimulated scattering",

abstract = "Temperature-dependent molecular dynamics of CS2 liquid are examined in femtosecond time-resolved impulsive stimulated scattering experiments. At temperatures T≤ 240 K, weakly oscillatory time-dependent responses are observed. These are interpreted in terms of librations of molecules about their local potential minima. The librations undergo rapid inhomogeneous dephasing. Temperature-dependent values of the configuration-averaged librational frequency and the extent of inhomogeneity in that frequency are determined.",

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AU - Ruhman, S.

AU - Kohler, Bern

AU - Joly, Alan G.

AU - Nelson, Keith A.

PY - 1987/10/30

Y1 - 1987/10/30

N2 - Temperature-dependent molecular dynamics of CS2 liquid are examined in femtosecond time-resolved impulsive stimulated scattering experiments. At temperatures T≤ 240 K, weakly oscillatory time-dependent responses are observed. These are interpreted in terms of librations of molecules about their local potential minima. The librations undergo rapid inhomogeneous dephasing. Temperature-dependent values of the configuration-averaged librational frequency and the extent of inhomogeneity in that frequency are determined.

AB - Temperature-dependent molecular dynamics of CS2 liquid are examined in femtosecond time-resolved impulsive stimulated scattering experiments. At temperatures T≤ 240 K, weakly oscillatory time-dependent responses are observed. These are interpreted in terms of librations of molecules about their local potential minima. The librations undergo rapid inhomogeneous dephasing. Temperature-dependent values of the configuration-averaged librational frequency and the extent of inhomogeneity in that frequency are determined.

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-2

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Intermolecular vibrational motion in CS₂ liquid at 165 ≤ T≥ 300 K observed by femtosecond time-resolved impulsive stimulated scattering

Abstract

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