International union of pure and applied chemistry analytical chemistry division commission on electro analytical chemistry thermodynamic functions of transfer of single ions from water to nonaqueous and mixed solventspart 2: Enthalpies and entropies of transfer to nonaqueous solvents

Y. Marcus*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

90 Scopus citations

Abstract

Literature data on the enthalpies and entropies of transfer of ions from water to nonaqueous solvents to the end of 1982 are compiled and evaluated according to stated criteria, including the extrathermodynamic assumption. Data, for which the tetraphenylarsonium tetraphenylborate assumption was not used were assigned low weights in the evaluation. The entropy data were subjected to the additional criterion of yielding with the enthalpy data the previously established Gibbs free energy data. Selected values are suggested on the basis of a weighted averaging procedure.

Original languageEnglish
Pages (from-to)1103-1128
Number of pages26
JournalPure and Applied Chemistry
Volume57
Issue number8
DOIs
StatePublished - 1 Jan 1985

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