TY - JOUR
T1 - International union of pure and applied chemistry analytical chemistry division commission on electro analytical chemistry thermodynamic functions of transfer of single ions from water to nonaqueous and mixed solventspart 2
T2 - Enthalpies and entropies of transfer to nonaqueous solvents
AU - Marcus, Y.
PY - 1985/1/1
Y1 - 1985/1/1
N2 - Literature data on the enthalpies and entropies of transfer of ions from water to nonaqueous solvents to the end of 1982 are compiled and evaluated according to stated criteria, including the extrathermodynamic assumption. Data, for which the tetraphenylarsonium tetraphenylborate assumption was not used were assigned low weights in the evaluation. The entropy data were subjected to the additional criterion of yielding with the enthalpy data the previously established Gibbs free energy data. Selected values are suggested on the basis of a weighted averaging procedure.
AB - Literature data on the enthalpies and entropies of transfer of ions from water to nonaqueous solvents to the end of 1982 are compiled and evaluated according to stated criteria, including the extrathermodynamic assumption. Data, for which the tetraphenylarsonium tetraphenylborate assumption was not used were assigned low weights in the evaluation. The entropy data were subjected to the additional criterion of yielding with the enthalpy data the previously established Gibbs free energy data. Selected values are suggested on the basis of a weighted averaging procedure.
UR - http://www.scopus.com/inward/record.url?scp=0007901475&partnerID=8YFLogxK
U2 - 10.1351/pac198557081103
DO - 10.1351/pac198557081103
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AN - SCOPUS:0007901475
SN - 0033-4545
VL - 57
SP - 1103
EP - 1128
JO - Pure and Applied Chemistry
JF - Pure and Applied Chemistry
IS - 8
ER -