Investigation of short lived radicals in aromatic nucleophilic substitution by use of nitroso compounds as scavengers

I. I. Bilkis; S. M. Shein

doi:10.1016/0040-4020(75)80110-4

Investigation of short lived radicals in aromatic nucleophilic substitution by use of nitroso compounds as scavengers

I. I. Bilkis^*
, S. M. Shein

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Radical intermediates formed in reaction of substituted nitrobenzene compounds with nucleophilic reagents have been trapped by t-nitrosobutane to yield nitroxide radicals which have been characterized in situ by ESR. The formation of short-lived radicals originating from reagents and solvents has been shown.

Original language	English
Pages (from-to)	969-971
Number of pages	3
Journal	Tetrahedron
Volume	31
Issue number	8
DOIs	https://doi.org/10.1016/0040-4020(75)80110-4
State	Published - 1975
Externally published	Yes

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title = "Investigation of short lived radicals in aromatic nucleophilic substitution by use of nitroso compounds as scavengers",

abstract = "Radical intermediates formed in reaction of substituted nitrobenzene compounds with nucleophilic reagents have been trapped by t-nitrosobutane to yield nitroxide radicals which have been characterized in situ by ESR. The formation of short-lived radicals originating from reagents and solvents has been shown.",

author = "Bilkis, \{I. I.\} and Shein, \{S. M.\}",

year = "1975",

doi = "10.1016/0040-4020(75)80110-4",

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journal = "Tetrahedron",

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T1 - Investigation of short lived radicals in aromatic nucleophilic substitution by use of nitroso compounds as scavengers

AU - Bilkis, I. I.

AU - Shein, S. M.

PY - 1975

Y1 - 1975

N2 - Radical intermediates formed in reaction of substituted nitrobenzene compounds with nucleophilic reagents have been trapped by t-nitrosobutane to yield nitroxide radicals which have been characterized in situ by ESR. The formation of short-lived radicals originating from reagents and solvents has been shown.

AB - Radical intermediates formed in reaction of substituted nitrobenzene compounds with nucleophilic reagents have been trapped by t-nitrosobutane to yield nitroxide radicals which have been characterized in situ by ESR. The formation of short-lived radicals originating from reagents and solvents has been shown.

UR - https://www.scopus.com/pages/publications/0342715886

U2 - 10.1016/0040-4020(75)80110-4

DO - 10.1016/0040-4020(75)80110-4

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AN - SCOPUS:0342715886

SN - 0040-4020

VL - 31

SP - 969

EP - 971

JO - Tetrahedron

JF - Tetrahedron

IS - 8

ER -

Investigation of short lived radicals in aromatic nucleophilic substitution by use of nitroso compounds as scavengers

Abstract

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