Ionic and molar volumes of room temperature ionic liquids

Yizhak Marcus*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

42 Scopus citations

Abstract

A large set of ionic volumes of the constituent ions of a variety of (non-protic) RTILs is used for the estimation of their molar volumes, hence their densities, at various temperatures by means of two fitting parameters only. The difference between the sum of the ionic volumes of the cation and the anion per mole and the actual molar volume is ascribed to the expansion of the RTIL on melting.

Original languageEnglish
Pages (from-to)289-293
Number of pages5
JournalJournal of Molecular Liquids
Volume209
DOIs
StatePublished - 11 Jun 2015

Bibliographical note

Publisher Copyright:
© 2015 Elsevier B.V.All rights reserved.

Keywords

  • Densities
  • Expansion on melting
  • Ionic volumes
  • Molar volumes
  • Room temperature ionic liquids

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