Is There a Nitroalkane Anomaly?

Noam Agmon

doi:10.1021/ja00527a003

Is There a Nitroalkane Anomaly?

Noam Agmon^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

The abnormal BrjSnsted slopes observed for nitroalkanes are interpreted as a variation in the work terms, which is caused by a variation in hydrogen bond strengths with the free energy for proton transfer, rather than as an anomaly in the proton- transfer stage itself.

Original language	English
Pages (from-to)	2164-2167
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	102
Issue number	7
DOIs	https://doi.org/10.1021/ja00527a003
State	Published - Mar 1980

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10.1021/ja00527a003

Cite this

@article{537a1cfa43f1488a85bf8da2812f939f,

title = "Is There a Nitroalkane Anomaly?",

abstract = "The abnormal BrjSnsted slopes observed for nitroalkanes are interpreted as a variation in the work terms, which is caused by a variation in hydrogen bond strengths with the free energy for proton transfer, rather than as an anomaly in the proton- transfer stage itself.",

author = "Noam Agmon",

year = "1980",

month = mar,

doi = "10.1021/ja00527a003",

language = "אנגלית",

volume = "102",

pages = "2164--2167",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",