Isomerization of allyl alcohols by a water soluble ruthenium catalyst in a two-liquid phase system

Yoel Sasson; Amikam Zoran; Jochanan Blum

doi:10.1016/0304-5102(79)80034-6

Isomerization of allyl alcohols by a water soluble ruthenium catalyst in a two-liquid phase system

Yoel Sasson, Amikam Zoran, Jochanan Blum^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The principle of two-liquid phase catalysis has been demonstrated in the transformation of heptane soluble allyl alcohols and aqueous μ₃-oxo-tri-ruthenium acetate to saturated ketones. The reaction with dec-1-en-3-ol was shown to take place at the liquids' interface while hex-1-en-3-ol and hept-1- en-ol undergo both interfacial and homogeneous isomerization.

Original language	English
Pages (from-to)	289-292
Number of pages	4
Journal	Journal of Molecular Catalysis
Volume	6
Issue number	4
DOIs	https://doi.org/10.1016/0304-5102(79)80034-6
State	Published - Oct 1979

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title = "Isomerization of allyl alcohols by a water soluble ruthenium catalyst in a two-liquid phase system",

abstract = "The principle of two-liquid phase catalysis has been demonstrated in the transformation of heptane soluble allyl alcohols and aqueous μ3-oxo-tri-ruthenium acetate to saturated ketones. The reaction with dec-1-en-3-ol was shown to take place at the liquids' interface while hex-1-en-3-ol and hept-1- en-ol undergo both interfacial and homogeneous isomerization.",

author = "Yoel Sasson and Amikam Zoran and Jochanan Blum",

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N2 - The principle of two-liquid phase catalysis has been demonstrated in the transformation of heptane soluble allyl alcohols and aqueous μ3-oxo-tri-ruthenium acetate to saturated ketones. The reaction with dec-1-en-3-ol was shown to take place at the liquids' interface while hex-1-en-3-ol and hept-1- en-ol undergo both interfacial and homogeneous isomerization.

AB - The principle of two-liquid phase catalysis has been demonstrated in the transformation of heptane soluble allyl alcohols and aqueous μ3-oxo-tri-ruthenium acetate to saturated ketones. The reaction with dec-1-en-3-ol was shown to take place at the liquids' interface while hex-1-en-3-ol and hept-1- en-ol undergo both interfacial and homogeneous isomerization.

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Isomerization of allyl alcohols by a water soluble ruthenium catalyst in a two-liquid phase system

Abstract

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