Kinetics of unimolecular breakdown. VIII. The Lindemann-Hinshelwood mechanism

R. D. Levine

doi:10.1063/1.1668027

Kinetics of unimolecular breakdown. VIII. The Lindemann-Hinshelwood mechanism

R. D. Levine^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A quantum-mechanical theory of thermal unimolecular breakdown based on the Lindemann-Hinshelwood mechanism is presented. The kinetic equation is derived on the basis of the averaged density operator of Karplus and Schwinger [Phys. Rev. 73, 1020 (1948)]. The kinetic equation is solved under stationary experimental conditions, and the pressure dependence of the rate of formation of products is related to the detailed time evolution of activated molecules.

Original language	English
Pages (from-to)	4556-4560
Number of pages	5
Journal	The Journal of Chemical Physics
Volume	48
Issue number	10
DOIs	https://doi.org/10.1063/1.1668027
State	Published - 1968

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abstract = "A quantum-mechanical theory of thermal unimolecular breakdown based on the Lindemann-Hinshelwood mechanism is presented. The kinetic equation is derived on the basis of the averaged density operator of Karplus and Schwinger [Phys. Rev. 73, 1020 (1948)]. The kinetic equation is solved under stationary experimental conditions, and the pressure dependence of the rate of formation of products is related to the detailed time evolution of activated molecules.",

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AB - A quantum-mechanical theory of thermal unimolecular breakdown based on the Lindemann-Hinshelwood mechanism is presented. The kinetic equation is derived on the basis of the averaged density operator of Karplus and Schwinger [Phys. Rev. 73, 1020 (1948)]. The kinetic equation is solved under stationary experimental conditions, and the pressure dependence of the rate of formation of products is related to the detailed time evolution of activated molecules.

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Kinetics of unimolecular breakdown. VIII. The Lindemann-Hinshelwood mechanism

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