TY - JOUR
T1 - KINETICS OF UNTERMINATED POLYMERIZATION REACTIONS.
AU - Baer, S.
AU - Kremer, M. L.
PY - 1979/2
Y1 - 1979/2
N2 - In the reported investigation, the kinetics of the intermediates in unterminated polymerization reactions were studied. It was found that in a first-order initiation (A) all intermediates accumulate monotonically. In a second-order initiation (B) the first intermediates pass through a maximum, whereas the later ones strictly accumulate. An initiator-started polymerization can follow course A or course B, depending on the initial ratio of the concentrations of the initiator and monomer.
AB - In the reported investigation, the kinetics of the intermediates in unterminated polymerization reactions were studied. It was found that in a first-order initiation (A) all intermediates accumulate monotonically. In a second-order initiation (B) the first intermediates pass through a maximum, whereas the later ones strictly accumulate. An initiator-started polymerization can follow course A or course B, depending on the initial ratio of the concentrations of the initiator and monomer.
UR - https://www.scopus.com/pages/publications/0018430451
U2 - 10.1002/pol.1979.170170215
DO - 10.1002/pol.1979.170170215
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AN - SCOPUS:0018430451
SN - 0449-296X
VL - 17
SP - 455
EP - 464
JO - J Polym Sci Polym Chem Ed
JF - J Polym Sci Polym Chem Ed
IS - 2
ER -