KINETICS OF UNTERMINATED POLYMERIZATION REACTIONS.

S. Baer; M. L. Kremer

doi:10.1002/pol.1979.170170215

KINETICS OF UNTERMINATED POLYMERIZATION REACTIONS.

S. Baer^*
, M. L. Kremer

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the reported investigation, the kinetics of the intermediates in unterminated polymerization reactions were studied. It was found that in a first-order initiation (A) all intermediates accumulate monotonically. In a second-order initiation (B) the first intermediates pass through a maximum, whereas the later ones strictly accumulate. An initiator-started polymerization can follow course A or course B, depending on the initial ratio of the concentrations of the initiator and monomer.

Original language	English
Pages (from-to)	455-464
Number of pages	10
Journal	J Polym Sci Polym Chem Ed
Volume	17
Issue number	2
DOIs	https://doi.org/10.1002/pol.1979.170170215
State	Published - Feb 1979

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title = "KINETICS OF UNTERMINATED POLYMERIZATION REACTIONS.",

abstract = "In the reported investigation, the kinetics of the intermediates in unterminated polymerization reactions were studied. It was found that in a first-order initiation (A) all intermediates accumulate monotonically. In a second-order initiation (B) the first intermediates pass through a maximum, whereas the later ones strictly accumulate. An initiator-started polymerization can follow course A or course B, depending on the initial ratio of the concentrations of the initiator and monomer.",

author = "S. Baer and Kremer, \{M. L.\}",

year = "1979",

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AB - In the reported investigation, the kinetics of the intermediates in unterminated polymerization reactions were studied. It was found that in a first-order initiation (A) all intermediates accumulate monotonically. In a second-order initiation (B) the first intermediates pass through a maximum, whereas the later ones strictly accumulate. An initiator-started polymerization can follow course A or course B, depending on the initial ratio of the concentrations of the initiator and monomer.

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KINETICS OF UNTERMINATED POLYMERIZATION REACTIONS.

Abstract

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