Lanthanide assisted cross-coupling of aryl bromides with triethylaluminum

Margarita Shenglof; Dmitri Gelman; Gary A. Molander; Jochanan Blum

doi:10.1016/j.tetlet.2003.09.147

Lanthanide assisted cross-coupling of aryl bromides with triethylaluminum

Margarita Shenglof, Dmitri Gelman, Gary A. Molander, Jochanan Blum^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Cerium trichloride, as well as some other lanthanide salts, promote the palladium-catalyzed cross-coupling of triethylaluminum with bromoarenes. The lanthanide compounds also increase the selectivity by diminishing the undesired hydrodebromination process.

Original language	English
Pages (from-to)	8593-8595
Number of pages	3
Journal	Tetrahedron Letters
Volume	44
Issue number	47
DOIs	https://doi.org/10.1016/j.tetlet.2003.09.147
State	Published - 17 Nov 2003

Bibliographical note

Funding Information:
We thank the United States–Israel Binational Science Foundation (BSF) for financial support of this study through grant No. 2000013.

Keywords

Aluminum
Bromoarenes
Cross-coupling
Lanthanide compounds

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10.1016/j.tetlet.2003.09.147

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title = "Lanthanide assisted cross-coupling of aryl bromides with triethylaluminum",

abstract = "Cerium trichloride, as well as some other lanthanide salts, promote the palladium-catalyzed cross-coupling of triethylaluminum with bromoarenes. The lanthanide compounds also increase the selectivity by diminishing the undesired hydrodebromination process.",

keywords = "Aluminum, Bromoarenes, Cross-coupling, Lanthanide compounds",

author = "Margarita Shenglof and Dmitri Gelman and Molander, {Gary A.} and Jochanan Blum",

note = "Funding Information: We thank the United States–Israel Binational Science Foundation (BSF) for financial support of this study through grant No. 2000013. ",

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T1 - Lanthanide assisted cross-coupling of aryl bromides with triethylaluminum

AU - Shenglof, Margarita

AU - Gelman, Dmitri

AU - Molander, Gary A.

AU - Blum, Jochanan

N1 - Funding Information: We thank the United States–Israel Binational Science Foundation (BSF) for financial support of this study through grant No. 2000013.

PY - 2003/11/17

Y1 - 2003/11/17

N2 - Cerium trichloride, as well as some other lanthanide salts, promote the palladium-catalyzed cross-coupling of triethylaluminum with bromoarenes. The lanthanide compounds also increase the selectivity by diminishing the undesired hydrodebromination process.

AB - Cerium trichloride, as well as some other lanthanide salts, promote the palladium-catalyzed cross-coupling of triethylaluminum with bromoarenes. The lanthanide compounds also increase the selectivity by diminishing the undesired hydrodebromination process.

KW - Aluminum

KW - Bromoarenes

KW - Cross-coupling

KW - Lanthanide compounds

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DO - 10.1016/j.tetlet.2003.09.147

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 47

ER -

Lanthanide assisted cross-coupling of aryl bromides with triethylaluminum

Abstract

Bibliographical note

Keywords

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