Length and velocity formulae in approximate oscillator strength calculations

M. Cohen; R. P. McEachran

doi:10.1016/0009-2614(72)87178-1

Length and velocity formulae in approximate oscillator strength calculations

M. Cohen^*
, R. P. McEachran

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The matrix element for electric dipole transitions is given correctly neither by the length formula nor by the velocity formula in the frozen core Hartree-Fock approximation, contrary to the assertion of Starace.

Original language	English
Pages (from-to)	201-204
Number of pages	4
Journal	Chemical Physics Letters
Volume	14
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(72)87178-1
State	Published - 15 May 1972

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title = "Length and velocity formulae in approximate oscillator strength calculations",

abstract = "The matrix element for electric dipole transitions is given correctly neither by the length formula nor by the velocity formula in the frozen core Hartree-Fock approximation, contrary to the assertion of Starace.",

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Length and velocity formulae in approximate oscillator strength calculations

Abstract

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