Ligand-metal cooperating PC(sp3)P pincer complexes as catalysts in olefin hydroformylation

Sanaa Musa, Oleg A. Filippov, Natalia V. Belkova, Elena S. Shubina, Gleb A. Silantyev, Lutz Ackermann, Dmitri Gelman*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

39 Scopus citations

Abstract

Ligand-metal cooperation: A new ligand-metal cooperating catalyst for the hydroformylation of olefins is described (see scheme). The mechanism of the H2 activation and C-H bond formation of the catalyst involves an intramolecular cooperation between the structurally remote functionality and the metal center and proceeds without change of the oxidation state of the metal.

Original languageAmerican English
Pages (from-to)16906-16909
Number of pages4
JournalChemistry - A European Journal
Volume19
Issue number50
DOIs
StatePublished - 9 Dec 2013

Keywords

  • catalysis
  • hydroformylation
  • ligand-metal cooperation
  • noninnocent ligands
  • pincer complexes

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