Abstract
Ligand-metal cooperation: A new ligand-metal cooperating catalyst for the hydroformylation of olefins is described (see scheme). The mechanism of the H2 activation and C-H bond formation of the catalyst involves an intramolecular cooperation between the structurally remote functionality and the metal center and proceeds without change of the oxidation state of the metal.
Original language | English |
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Pages (from-to) | 16906-16909 |
Number of pages | 4 |
Journal | Chemistry - A European Journal |
Volume | 19 |
Issue number | 50 |
DOIs | |
State | Published - 9 Dec 2013 |
Keywords
- catalysis
- hydroformylation
- ligand-metal cooperation
- noninnocent ligands
- pincer complexes