Ligand-metal cooperation in pcppincer complexes: Rational design and catalytic activity in acceptorless dehydrogenation of alcohols

Sanaa Musa; Irina Shaposhnikov; Shmuel Cohen; Dmitri Gelman

doi:10.1002/anie.201007367

Ligand-metal cooperation in pcppincer complexes: Rational design and catalytic activity in acceptorless dehydrogenation of alcohols

Sanaa Musa
, Irina Shaposhnikov
, Shmuel Cohen
, Dmitri Gelman^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

240 Scopus citations

Abstract

A helping hand: The dibenzobarrelene-based PCsp3Ppincer complex 1 was designed as a bifunctional catalyst for the acceptorless dehydrogenation of alcohols. The mechanism of the H₂ release involves interaction between the hydride ligand and the acidic sidearm in the intermediate 2 (red O, yellow Cl, green P, blue Ir). The feasibility of the complete catalytic cycle was studied using a stoichiometric model and the reaction was subsequently realized in a catalytic fashion.

Original language	English
Pages (from-to)	3533-3537
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	15
DOIs	https://doi.org/10.1002/anie.201007367
State	Published - 4 Apr 2011

Keywords

cooperative effects
dehydrogenation
homogeneous catalysis
iridium
pincer complexes

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abstract = "A helping hand: The dibenzobarrelene-based PCsp3Ppincer complex 1 was designed as a bifunctional catalyst for the acceptorless dehydrogenation of alcohols. The mechanism of the H2 release involves interaction between the hydride ligand and the acidic sidearm in the intermediate 2 (red O, yellow Cl, green P, blue Ir). The feasibility of the complete catalytic cycle was studied using a stoichiometric model and the reaction was subsequently realized in a catalytic fashion.",

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AU - Cohen, Shmuel

AU - Gelman, Dmitri

PY - 2011/4/4

Y1 - 2011/4/4

N2 - A helping hand: The dibenzobarrelene-based PCsp3Ppincer complex 1 was designed as a bifunctional catalyst for the acceptorless dehydrogenation of alcohols. The mechanism of the H2 release involves interaction between the hydride ligand and the acidic sidearm in the intermediate 2 (red O, yellow Cl, green P, blue Ir). The feasibility of the complete catalytic cycle was studied using a stoichiometric model and the reaction was subsequently realized in a catalytic fashion.

AB - A helping hand: The dibenzobarrelene-based PCsp3Ppincer complex 1 was designed as a bifunctional catalyst for the acceptorless dehydrogenation of alcohols. The mechanism of the H2 release involves interaction between the hydride ligand and the acidic sidearm in the intermediate 2 (red O, yellow Cl, green P, blue Ir). The feasibility of the complete catalytic cycle was studied using a stoichiometric model and the reaction was subsequently realized in a catalytic fashion.

KW - cooperative effects

KW - dehydrogenation

KW - homogeneous catalysis

KW - iridium

KW - pincer complexes

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JF - Angewandte Chemie - International Edition

IS - 15

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Ligand-metal cooperation in pcppincer complexes: Rational design and catalytic activity in acceptorless dehydrogenation of alcohols

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Keywords

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