Low viscosity reversed hexagonal mesophases induced by hydrophilic additives

Idit Amar-Yuli, Ellen Wachtel, Deborah E. Shalev, Abraham Aserin, Nissim Garti*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

This study reports on the formation of a low viscosity HII mesophase at room temperature upon addition of Transcutol (diethylene glycol mono ethyl ether) or ethanol to the ternary mixture of GMO (glycerol monooleate)/TAG (tricaprylin)/water. The microstructure and bulk properties were characterized in comparison with those of the low viscosity Hn mesophase formed in the ternary GMO/TAG/water mixture at elevated temperatures (35-40°C). We characterized the role of Transcutol or ethanol as inducers of disorder and surfactant mobility. The techniques used were rheology, differential scanning calorimetry (DSC), wide- and small-angle X-ray scattering (WAXS and SAXS, respectively), NMR (self-diffusion and 2H NMR), and Fourier transform infrared (FTIR) spectroscopies. The incorporation of either Transcutol or ethanol induced the formation of less ordered HII mesophases with smaller domain sizes and lattice parameters at room temperature (up to 30°C), similar to those found for the GMO/TAG/water mixture at more elevated temperatures (35-40°C). On the basis of our measurements, we suggest that Transcutol or ethanol causes dehydration of the GMO headgroups and enhances the mobility of the GMO chains. As a result, these two small molecules, which compete for water with the GMO polar headgroups, may increase the curvature of the cylindrical micelles and also perhaps reduce their length. This results in the formation of fluid HII structures at room temperature (up to 30°C). It is possible that these phases are a prelude to the H II-L2 transformation, which takes place above 35°C.

Original languageAmerican English
Pages (from-to)3971-3982
Number of pages12
JournalJournal of Physical Chemistry B
Volume112
Issue number13
DOIs
StatePublished - 3 Apr 2008

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