Magnetic and electronic properties of HOPG/MoF6 graphite intercalation compounds: An ESR study

D. Vaknin; D. Davidov; H. Selig; Y. Yeshurun

doi:10.1063/1.449096

Magnetic and electronic properties of HOPG/MoF₆ graphite intercalation compounds: An ESR study

D. Vaknin^*, D. Davidov, H. Selig, Y. Yeshurun

^*Corresponding author for this work

Racah Institute of Physics

Research output: Contribution to journal › Article › peer-review

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Abstract

The diamagnetic MoF6 molecule intercalates into graphite (HOPG) according to the reaction nC + MoF₆ → C_n⁺ ^x(MoF₆^-)_x(MoF₆) _1-x. Combination of ESR and magnetic susceptibility measurements indicate that the charge transfer is incomplete with x∼0.2. The system HOPG/ MoF₆ is unique in that ESR resonances due to both the 4d₁ intercalant species (MoF₆^-) and conduction carriers can be detected. The ESR spectra of stage III exhibit an additional resonance which is probably associated with graphite interior layers.

Original language	English
Pages (from-to)	3859-3862
Number of pages	4
Journal	The Journal of Chemical Physics
Volume	83
Issue number	8
DOIs	https://doi.org/10.1063/1.449096
State	Published - 1985

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title = "Magnetic and electronic properties of HOPG/MoF6 graphite intercalation compounds: An ESR study",

abstract = "The diamagnetic MoF6 molecule intercalates into graphite (HOPG) according to the reaction nC + MoF6 → Cn+ x(MoF6-)x(MoF6) 1-x. Combination of ESR and magnetic susceptibility measurements indicate that the charge transfer is incomplete with x∼0.2. The system HOPG/ MoF6 is unique in that ESR resonances due to both the 4d1 intercalant species (MoF6-) and conduction carriers can be detected. The ESR spectra of stage III exhibit an additional resonance which is probably associated with graphite interior layers.",

author = "D. Vaknin and D. Davidov and H. Selig and Y. Yeshurun",

year = "1985",

doi = "10.1063/1.449096",

language = "אנגלית",

volume = "83",

pages = "3859--3862",

journal = "The Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

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T1 - Magnetic and electronic properties of HOPG/MoF6 graphite intercalation compounds

T2 - An ESR study

AU - Vaknin, D.

AU - Davidov, D.

AU - Selig, H.

AU - Yeshurun, Y.

PY - 1985

Y1 - 1985

N2 - The diamagnetic MoF6 molecule intercalates into graphite (HOPG) according to the reaction nC + MoF6 → Cn+ x(MoF6-)x(MoF6) 1-x. Combination of ESR and magnetic susceptibility measurements indicate that the charge transfer is incomplete with x∼0.2. The system HOPG/ MoF6 is unique in that ESR resonances due to both the 4d1 intercalant species (MoF6-) and conduction carriers can be detected. The ESR spectra of stage III exhibit an additional resonance which is probably associated with graphite interior layers.

AB - The diamagnetic MoF6 molecule intercalates into graphite (HOPG) according to the reaction nC + MoF6 → Cn+ x(MoF6-)x(MoF6) 1-x. Combination of ESR and magnetic susceptibility measurements indicate that the charge transfer is incomplete with x∼0.2. The system HOPG/ MoF6 is unique in that ESR resonances due to both the 4d1 intercalant species (MoF6-) and conduction carriers can be detected. The ESR spectra of stage III exhibit an additional resonance which is probably associated with graphite interior layers.

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EP - 3862

JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

IS - 8

ER -

Magnetic and electronic properties of HOPG/MoF₆ graphite intercalation compounds: An ESR study

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