Magnetic behavior in solid solution systems: I. (MnMg)Tb2S4

L. Ben-Dor; I. Shilo

doi:10.1016/0022-4596(80)90468-5

Magnetic behavior in solid solution systems: I. (MnMg)Tb₂S₄

L. Ben-Dor^*
, I. Shilo

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The solid solutions in the system Mn_xMg_1−xTb₂S₄ for 0 ≤ x ≤ 1 all have the orthorhombic MnY₂S₄ structure, space group Cmc2₁. In the temperature range 77–300 K the materials are paramagnetic and the Curie-Weiss law is obeyed. At low temperatures, ca. 20 K, there is a deviation from linearity of the curve of χ⁻¹ vs T. The curves of magnetization as a function of the magnetic field at 4.2 K are reminiscent of saturation curves, especially for low values of x. The magnetic interactions between the metal ions are discussed.

Original language	English
Pages (from-to)	99-102
Number of pages	4
Journal	Journal of Solid State Chemistry
Volume	35
Issue number	1
DOIs	https://doi.org/10.1016/0022-4596(80)90468-5
State	Published - 1980

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title = "Magnetic behavior in solid solution systems: I. (MnMg)Tb2S4",

abstract = "The solid solutions in the system MnxMg1−xTb2S4 for 0 ≤ x ≤ 1 all have the orthorhombic MnY2S4 structure, space group Cmc21. In the temperature range 77–300 K the materials are paramagnetic and the Curie-Weiss law is obeyed. At low temperatures, ca. 20 K, there is a deviation from linearity of the curve of χ−1 vs T. The curves of magnetization as a function of the magnetic field at 4.2 K are reminiscent of saturation curves, especially for low values of x. The magnetic interactions between the metal ions are discussed.",

author = "L. Ben-Dor and I. Shilo",

year = "1980",

doi = "10.1016/0022-4596(80)90468-5",

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AU - Ben-Dor, L.

AU - Shilo, I.

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N2 - The solid solutions in the system MnxMg1−xTb2S4 for 0 ≤ x ≤ 1 all have the orthorhombic MnY2S4 structure, space group Cmc21. In the temperature range 77–300 K the materials are paramagnetic and the Curie-Weiss law is obeyed. At low temperatures, ca. 20 K, there is a deviation from linearity of the curve of χ−1 vs T. The curves of magnetization as a function of the magnetic field at 4.2 K are reminiscent of saturation curves, especially for low values of x. The magnetic interactions between the metal ions are discussed.

AB - The solid solutions in the system MnxMg1−xTb2S4 for 0 ≤ x ≤ 1 all have the orthorhombic MnY2S4 structure, space group Cmc21. In the temperature range 77–300 K the materials are paramagnetic and the Curie-Weiss law is obeyed. At low temperatures, ca. 20 K, there is a deviation from linearity of the curve of χ−1 vs T. The curves of magnetization as a function of the magnetic field at 4.2 K are reminiscent of saturation curves, especially for low values of x. The magnetic interactions between the metal ions are discussed.

UR - https://www.scopus.com/pages/publications/0011584385

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JF - Journal of Solid State Chemistry

IS - 1

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Magnetic behavior in solid solution systems: I. (MnMg)Tb₂S₄

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