Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

Ahmad Masarwa; Alois Fürstner; Ilan Marek

doi:10.1039/b910465h

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

Ahmad Masarwa, Alois Fürstner, Ilan Marek^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

Pd(ii)- and Pt(ii)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.

Original language	English
Pages (from-to)	5760-5762
Number of pages	3
Journal	Chemical Communications
Issue number	38
DOIs	https://doi.org/10.1039/b910465h
State	Published - 2009
Externally published	Yes

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title = "Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters",

abstract = "Pd(ii)- and Pt(ii)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.",

author = "Ahmad Masarwa and Alois F{\"u}rstner and Ilan Marek",

year = "2009",

doi = "10.1039/b910465h",

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publisher = "Royal Society of Chemistry",

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AU - Fürstner, Alois

AU - Marek, Ilan

PY - 2009

Y1 - 2009

N2 - Pd(ii)- and Pt(ii)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.

AB - Pd(ii)- and Pt(ii)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.

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DO - 10.1039/b910465h

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AN - SCOPUS:70349324706

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

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