TY - JOUR
T1 - Metal-polymer composites
T2 - Synthesis and characterization of polyaniline and other polymer αSilver compositions
AU - Nesher, Guy
AU - Marom, Gad
AU - Avnir, David
PY - 2008/7/8
Y1 - 2008/7/8
N2 - A method was developed for the entrapment of water-insoluble hydrophobic polymers in a metallic matrix, thus generalizing further the routes for obtaining the novel organics@metal composite materials. The reaction took place in an organic phase using the reduction of metal ions by DMF in the presence of water. The reductive entrapment of polyaniline was studied in detail using XRD, SEM, BET, TGA, UV-vis, XPS, and density measurements, and the mechanism of the entrapment was established. The scope of this approach is demonstrated by entrapment of two additional hydrophobic polymers, polystyrene and polyacrylonitrile.
AB - A method was developed for the entrapment of water-insoluble hydrophobic polymers in a metallic matrix, thus generalizing further the routes for obtaining the novel organics@metal composite materials. The reaction took place in an organic phase using the reduction of metal ions by DMF in the presence of water. The reductive entrapment of polyaniline was studied in detail using XRD, SEM, BET, TGA, UV-vis, XPS, and density measurements, and the mechanism of the entrapment was established. The scope of this approach is demonstrated by entrapment of two additional hydrophobic polymers, polystyrene and polyacrylonitrile.
UR - http://www.scopus.com/inward/record.url?scp=47749150677&partnerID=8YFLogxK
U2 - 10.1021/cm800657j
DO - 10.1021/cm800657j
M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???
AN - SCOPUS:47749150677
SN - 0897-4756
VL - 20
SP - 4425
EP - 4432
JO - Chemistry of Materials
JF - Chemistry of Materials
IS - 13
ER -