TY - JOUR
T1 - Mild, aqueous, aerobic, catalytic oxidation of methane to methanol and acetaldehyde catalyzed by a supported bipyrimidinylplatinum-polyoxometalate hybrid compound
AU - Bar-Nahum, Itsik
AU - Khenkin, Alexander M.
AU - Neumann, Ronny
PY - 2004/8/25
Y1 - 2004/8/25
N2 - We have demonstrated that a bipyrimidinylplatinum-polyoxometalate, [Pt(Mebipym)Cl2]+[H4PV2Mo10O40]-, supported on silica is an active catalyst for the aerobic oxidation of methane to methanol in water under mild reaction conditions. Further oxidation of methanol yields acetaldehyde. The presence of the polyoxometalate is presumed to allow the facile oxidation of a Pt(II) intermediate to a Pt(IV) intermediate and to aid in the addition of methane to the Pt catalytic center.
AB - We have demonstrated that a bipyrimidinylplatinum-polyoxometalate, [Pt(Mebipym)Cl2]+[H4PV2Mo10O40]-, supported on silica is an active catalyst for the aerobic oxidation of methane to methanol in water under mild reaction conditions. Further oxidation of methanol yields acetaldehyde. The presence of the polyoxometalate is presumed to allow the facile oxidation of a Pt(II) intermediate to a Pt(IV) intermediate and to aid in the addition of methane to the Pt catalytic center.
UR - http://www.scopus.com/inward/record.url?scp=4143151730&partnerID=8YFLogxK
U2 - 10.1021/ja0493547
DO - 10.1021/ja0493547
M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???
AN - SCOPUS:4143151730
SN - 0002-7863
VL - 126
SP - 10236
EP - 10237
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 33
ER -