Molecular and crystal structures of a class of push-pull quinonoid compounds with potential nonlinear optical applications

M. Ravi; Shmuel Cohen; Israel Agranat; T. P. Radhakrishnan

doi:10.1007/978-3-319-19827-9_22

Molecular and crystal structures of a class of push-pull quinonoid compounds with potential nonlinear optical applications

M. Ravi, Shmuel Cohen, Israel Agranat, T. P. Radhakrishnan^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

1 Scopus citations

Abstract

Molecular and crystal structures of three compounds with electron donor-conjugation unit- electron acceptor framework are reported where the conjugation unit is formally a quinonoid ring. Semiempirical quantum chemical calculations indicate large hyperpolarizabilities in these push-pull molecules. Since all the crystal structures are found to belong to centrosymmetric space groups, modifications are necessary for quadratic nonlinear optical applications.

Original language	English
Title of host publication	Science of Crystal Structures
Subtitle of host publication	Highlights in Crystallography
Publisher	Springer International Publishing
Pages	205-211
Number of pages	7
ISBN (Electronic)	9783319198279
ISBN (Print)	9783319198262
DOIs	https://doi.org/10.1007/978-3-319-19827-9_22
State	Published - 9 Sep 2015

Bibliographical note

Publisher Copyright:
© Springer International Publishing Switzerland 2015. All rights reserved.

Keywords

Crystal structures
Hyperpolarizability
Nonlinear optics
Push-pull quinonoids

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10.1007/978-3-319-19827-9_22

Cite this

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Molecular and crystal structures of a class of push-pull quinonoid compounds with potential nonlinear optical applications. / Ravi, M.; Cohen, Shmuel; Agranat, Israel et al.
Science of Crystal Structures: Highlights in Crystallography. Springer International Publishing, 2015. p. 205-211.

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

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KW - Hyperpolarizability

KW - Nonlinear optics

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Molecular and crystal structures of a class of push-pull quinonoid compounds with potential nonlinear optical applications

Abstract

Bibliographical note

Keywords

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