Molecular oxygen activation by a ruthenium-substituted 'sandwich' type polyoxometalate

Keyphrases

• Ruthenium 100%
• Molecular Oxygen Activation 100%
• Sandwich-type Polyoxometalate 100%
• Dioxygen 75%
• Induction Period 75%
• Adamantane 75%
• Reaction Rate 50%
• Molecular Oxygen 50%
• Kinetic Study 50%
• Ruthenium(IV) 50%
• Cyclooctatetraene 50%
• Ruthenium(III) 50%
• Methyl 25%
• Transition State 25%
• 5,5-dimethyl-1-pyrroline N-oxide 25%
• Spin Trapping 25%
• Oxygenation 25%
• Active Species 25%
• Stoichiometry 25%
• Low Entropy 25%
• UV-VIS Spectroscopy 25%
• Hydroxylation 25%
• Kinetic Analysis 25%
• Reducing Agent 25%
• Oxidation Mechanism 25%
• Zero Order 25%
• Reaction Temperature 25%
• Highly Selective 25%
• Reaction Mixture 25%
• Highly Ordered 25%
• IR Spectroscopy 25%
• Zn(II) 25%
• Peroxo 25%
• UV-IR 25%
• Polyoxometalates 25%
• Rate Dependence 25%
• Spectroscopic Evidence 25%
• Co(II) 25%
• ESR Spectra 25%
• Nonradical Oxidation 25%
• Dioxygenase 25%
• Substituted Polyoxometalate 25%
• Oxo Species 25%
• Regioselective Hydroxylation 25%
• Oxygen Donor 25%
• Peroxo Intermediates 25%
• Selective Epoxidation 25%
• Alkene Oxidation 25%
• Activation Entropy 25%
• Reaction Stoichiometry 25%
• Oxide Composition 25%
• Catalytic Epoxidation 25%
• Coordination Studies 25%
• Zn-Co 25%

Chemistry

• Ruthenium 100%
• Dioxygen 100%
• Polyoxometalate 100%
• Adamantane 37%
• formation 37%
• Kinetic Study 25%
• Reaction Stoichiometry 25%
• hydroxylation 25%
• epoxidation 25%
• 1-Pyrroline 12%
• N-Oxide 12%
• Transition State 12%
• Donor 12%
• UV/VIS Spectroscopy 12%
• Reducing Agent 12%
• Kinetic Method 12%
• ESR Spectrum 12%
• Dioxygenase 12%
• IR spectroscopy 12%
• oxidation of alkenes 12%
• Trans-Cyclooctene 12%
• Complex Formation 12%