Multiple reductive cleavage of calixarene diethyl phosphate esters: A route to [1n]metacyclophanes

Zafrir Goren; Silvio E. Biali

doi:10.1039/P19900001484

Multiple reductive cleavage of calixarene diethyl phosphate esters: A route to [1ⁿ]metacyclophanes

Zafrir Goren
, Silvio E. Biali^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

89 Scopus citations

Abstract

The OH groups of p-t-butylcalix[n]arene (n= 4 and 8) were converted into diethyl phosphate esters and reductively cleaved by treatment with K/NH₃ to yield tetra-p-t-butyl[1⁴]- and octa-p-t-butyl[1⁸]metacyclophanes (4) and (7).

Original language	English
Pages (from-to)	1484-1487
Number of pages	4
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	5
DOIs	https://doi.org/10.1039/P19900001484
State	Published - 1990

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@article{1dadda44c41c43e0867fab58b99a302f,

title = "Multiple reductive cleavage of calixarene diethyl phosphate esters: A route to [1n]metacyclophanes",

abstract = "The OH groups of p-t-butylcalix[n]arene (n= 4 and 8) were converted into diethyl phosphate esters and reductively cleaved by treatment with K/NH3 to yield tetra-p-t-butyl[14]- and octa-p-t-butyl[18]metacyclophanes (4) and (7).",

author = "Zafrir Goren and Biali, \{Silvio E.\}",

year = "1990",

doi = "10.1039/P19900001484",

language = "אנגלית",

pages = "1484--1487",

journal = "Journal of the Chemical Society, Perkin Transactions 1",

issn = "1470-4358",

publisher = "Chemical Society",

number = "5",

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T1 - Multiple reductive cleavage of calixarene diethyl phosphate esters

T2 - A route to [1n]metacyclophanes

AU - Goren, Zafrir

AU - Biali, Silvio E.

PY - 1990

Y1 - 1990

N2 - The OH groups of p-t-butylcalix[n]arene (n= 4 and 8) were converted into diethyl phosphate esters and reductively cleaved by treatment with K/NH3 to yield tetra-p-t-butyl[14]- and octa-p-t-butyl[18]metacyclophanes (4) and (7).

AB - The OH groups of p-t-butylcalix[n]arene (n= 4 and 8) were converted into diethyl phosphate esters and reductively cleaved by treatment with K/NH3 to yield tetra-p-t-butyl[14]- and octa-p-t-butyl[18]metacyclophanes (4) and (7).

UR - https://www.scopus.com/pages/publications/37049089386

U2 - 10.1039/P19900001484

DO - 10.1039/P19900001484

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AN - SCOPUS:37049089386

SN - 1470-4358

SP - 1484

EP - 1487

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

IS - 5

ER -

Multiple reductive cleavage of calixarene diethyl phosphate esters: A route to [1ⁿ]metacyclophanes

Abstract

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