N-Heterocyclic Carbene Based Nanolayer for Copper Film Oxidation Mitigation

Iris Berg, Einav Amit, Lillian Hale, F. Dean Toste, Elad Gross*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

The wide use of copper is limited by its rapid oxidation. Main oxidation mitigation approaches involve alloying or surface passivation technologies. However, surface alloying often modifies the physical properties of copper, while surface passivation is characterized by limited thermal and chemical stability. Herein, we demonstrate an electrochemical approach for surface-anchoring of an N-heterocyclic carbene (NHC) nanolayer on a copper electrode by electro-deposition of alkyne-functionalized imidazolium cations. Water reduction reaction generated a high concentration of hydroxide ions that induced deprotonation of imidazolium cations and self-assembly of NHCs on the copper electrode. In addition, alkyne group deprotonation enabled on-surface polymerization by coupling surface-anchored and solvated NHCs, which resulted in a 2 nm thick NHC-nanolayer. Copper film coated with a NHC-nanolayer demonstrated high oxidation resistance at elevated temperatures and under alkaline conditions.

Original languageAmerican English
Article numbere202201093
JournalAngewandte Chemie - International Edition
Volume61
Issue number25
DOIs
StatePublished - 20 Jun 2022

Bibliographical note

Publisher Copyright:
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.

Keywords

  • N-Heterocyclic Carbenes
  • Self-Assembled Monolayers
  • Surface Coating

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