TY - JOUR
T1 - Near-Threshold Photodetachment Cross Section of (SF6)n- Cluster Anions
T2 - The Ion Core Structure
AU - Luzon, Itamar
AU - Nagler, Maoz
AU - Chandrasekaran, Vijayanand
AU - Heber, Oded
AU - Strasser, Daniel
N1 - Publisher Copyright:
© 2015 American Chemical Society.
PY - 2016/1/21
Y1 - 2016/1/21
N2 - Photodetachment cross sections as a function of photon energy are measured for cold (SF6)n- cluster anions stored in an electrostatic ion beam trap. Absolute photodetachment cross sections near the adiabatic limit are reported. The strong dependence of the SF6- absolute photodetachment cross section on the anion equilibrium bond length leads to the conclusion that the excess charge is localized on a SF6- ion core that is only subtly perturbed by the neighboring cluster units.
AB - Photodetachment cross sections as a function of photon energy are measured for cold (SF6)n- cluster anions stored in an electrostatic ion beam trap. Absolute photodetachment cross sections near the adiabatic limit are reported. The strong dependence of the SF6- absolute photodetachment cross section on the anion equilibrium bond length leads to the conclusion that the excess charge is localized on a SF6- ion core that is only subtly perturbed by the neighboring cluster units.
UR - https://www.scopus.com/pages/publications/84955482376
U2 - 10.1021/acs.jpca.5b09967
DO - 10.1021/acs.jpca.5b09967
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AN - SCOPUS:84955482376
SN - 1089-5639
VL - 120
SP - 221
EP - 226
JO - Journal of Physical Chemistry A
JF - Journal of Physical Chemistry A
IS - 2
ER -