Negative dielectric loss phenomenon in porous sol-gel glasses

Ekaterina Axelrod, Alexander Puzenko, Yaara Haruvy, Renata Reisfeld, Yuri Feldman*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

28 Scopus citations


The broadband dielectric spectroscopy method was employed to investigate glasses of a fine porosity produced via regular and fast sol-gel routes with different catalysts. The study was carried out in the frequency range 20 Hz to 1 MHz and temperature interval -100 to +300 °C. The process discussed in the paper demonstrates unusual dielectric behavior. Dielectric losses of this process are negative, in certain regions of frequency and temperature, and the corresponding real part of the dielectric permittivity increases with increasing frequencies, according to Kramers-Kronig relationships. This exceptional process is located in different temperature regions for each sample. The concentration and type of acids, used as catalysts, influence the amplitude and the temperature-frequency ranges of the negative losses process (NLP). In order to decipher the physical nature of the process, the experimental study has been accompanied by a theoretical one. It was shown that the NLP in the porous sol-gel samples can be attributed to the local non-compensated matrix-anchored charges, which accumulate both inside the glassy matrix bulk and on the interface of the pores therein.

Original languageAmerican English
Pages (from-to)4166-4173
Number of pages8
JournalJournal of Non-Crystalline Solids
Issue number40-41 SPEC. ISS.
StatePublished - 1 Nov 2006

Bibliographical note

Funding Information:
The authors wish to thank Professor R. Richert (Arizona State University, USA) for his helpful discussions, and for his special kindness in carrying out dielectric measurements of our samples, by an alternative equipment, to reconfirm the existence of the NLP phenomena. Our thanks go also to Dr T. Saraidarov for help in the sol–gel sample preparation. One of the authors (E.A.) acknowledges the Eshkol fellowship of the Israeli Ministry of Science for the financial support during the research activity.


  • Dielectric properties
  • Relaxation, electric modulus
  • Sol-gels (xerogels)


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