TY - JOUR
T1 - New double salt [PCl4]3[TiCl6][PCl6] and related compounds in the PCl5TiCl4 system. Synthesis and structural determination by Raman spectra and X-ray analysis
AU - Shamir, Jacob
AU - Schneider, Shlomo
AU - Bino, Avi
AU - Cohen, Shmuel
PY - 1986/1/15
Y1 - 1986/1/15
N2 - The preparation of the newly identified double salt [PCl4]3[TiCl6][PCl6] is described herein. Its structure is elucidated by both X-ray analysis and Raman spectrum. This compound is tetragonal, space group P42/mbc with a = 14.648(1) Å, c = 13.922(1) Å, V = 2987(1) Å3 and Z = 4, and is isostructural with the related tin compound. The structure was refined by least-squares to R = 4.3%, using 668 observed reflections. Raman spectra of [PCl4]2[Ti2Cl10] and [PCl4][Ti2Cl9] were also reinvestigated and, as a result, some reassignments are proposed.
AB - The preparation of the newly identified double salt [PCl4]3[TiCl6][PCl6] is described herein. Its structure is elucidated by both X-ray analysis and Raman spectrum. This compound is tetragonal, space group P42/mbc with a = 14.648(1) Å, c = 13.922(1) Å, V = 2987(1) Å3 and Z = 4, and is isostructural with the related tin compound. The structure was refined by least-squares to R = 4.3%, using 668 observed reflections. Raman spectra of [PCl4]2[Ti2Cl10] and [PCl4][Ti2Cl9] were also reinvestigated and, as a result, some reassignments are proposed.
UR - http://www.scopus.com/inward/record.url?scp=0001489413&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)84643-5
DO - 10.1016/S0020-1693(00)84643-5
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AN - SCOPUS:0001489413
SN - 0020-1693
VL - 111
SP - 141
EP - 147
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 2
ER -