New possible mode of ligand-metal cooperation in PC(sp3)P pincer complexes

Sanaa Musa, Ronit Romm, Clarite Azerraf, Sebastian Kozuch, Dmitri Gelman*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

29 Scopus citations

Abstract

Ligand-metal cooperation in iridium and platinum complexes bearing tricyclic dibenzobarrelene-based PC(sp3)P pincer ligands is discussed. We demonstrated that the carbon-metal bond in these complexes may be efficiently cleaved and regenerated via 1,2-addition/elimination reactions.

Original languageAmerican English
Pages (from-to)8760-8763
Number of pages4
JournalDalton Transactions
Volume40
Issue number35
DOIs
StatePublished - 21 Sep 2011

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