Non-Arrhenius behavior of the F+H2 reaction rate at 293-700 K

M. A. Ioffe; Yu M. Gershenzon; V. B. Rozenshtein; S. Ya Umanskii

doi:10.1016/S0009-2614(89)87273-2

Non-Arrhenius behavior of the F+H₂ reaction rate at 293-700 K

M. A. Ioffe^*
, Yu M. Gershenzon
, V. B. Rozenshtein
, S. Ya Umanskii

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Non-Arrhenius behavior was observed in the temperature range 293-700 K for the absolute rate constant for the reaction F + H₂ using an EPR spectrometer combined with a fast-flow system. The measured rate constant (in cm³/s) fits the expression k = 2.9 × 10^-13 T exp[-(1390±440)/RT].

Original language	English
Pages (from-to)	131-134
Number of pages	4
Journal	Chemical Physics Letters
Volume	154
Issue number	2
DOIs	https://doi.org/10.1016/S0009-2614(89)87273-2
State	Published - 13 Jan 1989
Externally published	Yes

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10.1016/S0009-2614(89)87273-2

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title = "Non-Arrhenius behavior of the F+H2 reaction rate at 293-700 K",

abstract = "Non-Arrhenius behavior was observed in the temperature range 293-700 K for the absolute rate constant for the reaction F + H2 using an EPR spectrometer combined with a fast-flow system. The measured rate constant (in cm3/s) fits the expression k = 2.9 × 10-13 T exp[-(1390±440)/RT].",

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AU - Ioffe, M. A.

AU - Gershenzon, Yu M.

AU - Rozenshtein, V. B.

AU - Umanskii, S. Ya

PY - 1989/1/13

Y1 - 1989/1/13

N2 - Non-Arrhenius behavior was observed in the temperature range 293-700 K for the absolute rate constant for the reaction F + H2 using an EPR spectrometer combined with a fast-flow system. The measured rate constant (in cm3/s) fits the expression k = 2.9 × 10-13 T exp[-(1390±440)/RT].

AB - Non-Arrhenius behavior was observed in the temperature range 293-700 K for the absolute rate constant for the reaction F + H2 using an EPR spectrometer combined with a fast-flow system. The measured rate constant (in cm3/s) fits the expression k = 2.9 × 10-13 T exp[-(1390±440)/RT].

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JO - Chemical Physics Letters

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Non-Arrhenius behavior of the F+H₂ reaction rate at 293-700 K

Abstract

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