Nonmonotonic temperature dependence of the rates of ion-molecule reactions

Eran Rabani; D. M. Charutz; R. D. Levine

doi:10.1021/j100179a010

Nonmonotonic temperature dependence of the rates of ion-molecule reactions

Eran Rabani, D. M. Charutz, R. D. Levine

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A minimum in the temperature dependence of the reaction rate of fast reactions can be due to a double minimum potential along the reaction coordinate. The two important points are the steric effects of the central barrier along the reaction coordinate and the extensive recrossing of this barrier. General considerations and detailed classical trajectory computations are presented.

Original language	English
Pages (from-to)	10551-10553
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	95
Issue number	26
DOIs	https://doi.org/10.1021/j100179a010
State	Published - 1991

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title = "Nonmonotonic temperature dependence of the rates of ion-molecule reactions",

abstract = "A minimum in the temperature dependence of the reaction rate of fast reactions can be due to a double minimum potential along the reaction coordinate. The two important points are the steric effects of the central barrier along the reaction coordinate and the extensive recrossing of this barrier. General considerations and detailed classical trajectory computations are presented.",

author = "Eran Rabani and Charutz, {D. M.} and Levine, {R. D.}",

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AB - A minimum in the temperature dependence of the reaction rate of fast reactions can be due to a double minimum potential along the reaction coordinate. The two important points are the steric effects of the central barrier along the reaction coordinate and the extensive recrossing of this barrier. General considerations and detailed classical trajectory computations are presented.

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Nonmonotonic temperature dependence of the rates of ion-molecule reactions

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