Novel trans-spanned palladium complexes as efficient catalysts in mild and amine-free cyanation of aryl bromides under air

Olga Grossman; Dmitri Gelman

doi:10.1021/ol0601038

Novel trans-spanned palladium complexes as efficient catalysts in mild and amine-free cyanation of aryl bromides under air

Olga Grossman
, Dmitri Gelman^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

186 Scopus citations

Abstract

The use of a novel trans-spanned palladium complex as an efficient and selective catalyst in the cyanation of aryl halides is described. The suggested reaction conditions are mild, exhibit good scope of substrates, and circumvent the need for an inert atmosphere and amine co-ligands.

Original language	English
Pages (from-to)	1189-1191
Number of pages	3
Journal	Organic Letters
Volume	8
Issue number	6
DOIs	https://doi.org/10.1021/ol0601038
State	Published - 16 Mar 2006

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title = "Novel trans-spanned palladium complexes as efficient catalysts in mild and amine-free cyanation of aryl bromides under air",

abstract = "The use of a novel trans-spanned palladium complex as an efficient and selective catalyst in the cyanation of aryl halides is described. The suggested reaction conditions are mild, exhibit good scope of substrates, and circumvent the need for an inert atmosphere and amine co-ligands.",

author = "Olga Grossman and Dmitri Gelman",

year = "2006",

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doi = "10.1021/ol0601038",

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T1 - Novel trans-spanned palladium complexes as efficient catalysts in mild and amine-free cyanation of aryl bromides under air

AU - Grossman, Olga

AU - Gelman, Dmitri

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N2 - The use of a novel trans-spanned palladium complex as an efficient and selective catalyst in the cyanation of aryl halides is described. The suggested reaction conditions are mild, exhibit good scope of substrates, and circumvent the need for an inert atmosphere and amine co-ligands.

AB - The use of a novel trans-spanned palladium complex as an efficient and selective catalyst in the cyanation of aryl halides is described. The suggested reaction conditions are mild, exhibit good scope of substrates, and circumvent the need for an inert atmosphere and amine co-ligands.

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JO - Organic Letters

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Novel trans-spanned palladium complexes as efficient catalysts in mild and amine-free cyanation of aryl bromides under air

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