Nuclear magnetic resonance study of selected derivatives of 2,8,9‐trioxa‐5‐aza‐1‐silatricyclo[3.3.3.01,5]undecane (silatrane)

Jon M. Bellama; J. Dirk Nies; Nava Ben‐Zvi

doi:10.1002/mrc.1260240903

Nuclear magnetic resonance study of selected derivatives of 2,8,9‐trioxa‐5‐aza‐1‐silatricyclo[3.3.3.0^1,5]undecane (silatrane)

Jon M. Bellama^*
, J. Dirk Nies
, Nava Ben‐Zvi

^*Corresponding author for this work

Department of Science Teaching

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The ¹H, ¹³C and ²⁹Si nuclear magnetic resonance spectra of the parent compound and twelve derivatives of 2,8,9‐trioxa‐5‐aza‐1‐silatricyclo[3.3.3.0^1,5]undecane (silatrane) are discussed. Effective Taft polarity constants for the silatrane substituents are proposed. An equation is developed to correlate the ²⁹Si NMR chemical shifts of the silatranes with the corresponding organo‐triethoxysilanes.

Original language	English
Pages (from-to)	748-753
Number of pages	6
Journal	Magnetic Resonance in Chemistry
Volume	24
Issue number	9
DOIs	https://doi.org/10.1002/mrc.1260240903
State	Published - Sep 1986

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title = "Nuclear magnetic resonance study of selected derivatives of 2,8,9‐trioxa‐5‐aza‐1‐silatricyclo[3.3.3.01,5]undecane (silatrane)",

abstract = "The 1H, 13C and 29Si nuclear magnetic resonance spectra of the parent compound and twelve derivatives of 2,8,9‐trioxa‐5‐aza‐1‐silatricyclo[3.3.3.01,5]undecane (silatrane) are discussed. Effective Taft polarity constants for the silatrane substituents are proposed. An equation is developed to correlate the 29Si NMR chemical shifts of the silatranes with the corresponding organo‐triethoxysilanes.",

author = "Bellama, \{Jon M.\} and Nies, \{J. Dirk\} and Nava Ben‐Zvi",

year = "1986",

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T1 - Nuclear magnetic resonance study of selected derivatives of 2,8,9‐trioxa‐5‐aza‐1‐silatricyclo[3.3.3.01,5]undecane (silatrane)

AU - Bellama, Jon M.

AU - Nies, J. Dirk

AU - Ben‐Zvi, Nava

PY - 1986/9

Y1 - 1986/9

N2 - The 1H, 13C and 29Si nuclear magnetic resonance spectra of the parent compound and twelve derivatives of 2,8,9‐trioxa‐5‐aza‐1‐silatricyclo[3.3.3.01,5]undecane (silatrane) are discussed. Effective Taft polarity constants for the silatrane substituents are proposed. An equation is developed to correlate the 29Si NMR chemical shifts of the silatranes with the corresponding organo‐triethoxysilanes.

AB - The 1H, 13C and 29Si nuclear magnetic resonance spectra of the parent compound and twelve derivatives of 2,8,9‐trioxa‐5‐aza‐1‐silatricyclo[3.3.3.01,5]undecane (silatrane) are discussed. Effective Taft polarity constants for the silatrane substituents are proposed. An equation is developed to correlate the 29Si NMR chemical shifts of the silatranes with the corresponding organo‐triethoxysilanes.

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DO - 10.1002/mrc.1260240903

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JO - Magnetic Resonance in Chemistry

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ER -

Nuclear magnetic resonance study of selected derivatives of 2,8,9‐trioxa‐5‐aza‐1‐silatricyclo[3.3.3.0^1,5]undecane (silatrane)

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