Observation of Nd3+ paramagnetic resonance in intermetallic compounds

H. D. Dokter; D. Davidov; D. Shaltiel

doi:10.1016/0304-8853(78)90157-9

Observation of Nd³⁺ paramagnetic resonance in intermetallic compounds

H. D. Dokter^*, D. Davidov, D. Shaltiel

^*Corresponding author for this work

Racah Institute of Physics

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

We report an ESR study of Nd³⁺ in the cubic d band intermetallic compounds LuRh₂ and LuIr₂. The g value was found to be g = 2.62 +- 0.01 for both compounds which is close to that expected for a γ₆ ground state crystalline field splitting of the Nd 4f³ (J = 9/2) configuration. The hyperfine constants appropriate to ^{1 4 3}Nd and ^{1 4 5}Nd were found to be smaller than the free ionic values. This decrease is attributed to conduction electrons effects.

Original language	English
Pages (from-to)	82-83
Number of pages	2
Journal	Journal of Magnetism and Magnetic Materials
Volume	7
Issue number	1-4
DOIs	https://doi.org/10.1016/0304-8853(78)90157-9
State	Published - 1978

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abstract = "We report an ESR study of Nd3+ in the cubic d band intermetallic compounds LuRh2 and LuIr2. The g value was found to be g = 2.62 +- 0.01 for both compounds which is close to that expected for a γ6 ground state crystalline field splitting of the Nd 4f3 (J = 9/2) configuration. The hyperfine constants appropriate to 1 4 3Nd and 1 4 5Nd were found to be smaller than the free ionic values. This decrease is attributed to conduction electrons effects.",

author = "Dokter, {H. D.} and D. Davidov and D. Shaltiel",

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AU - Dokter, H. D.

AU - Davidov, D.

AU - Shaltiel, D.

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N2 - We report an ESR study of Nd3+ in the cubic d band intermetallic compounds LuRh2 and LuIr2. The g value was found to be g = 2.62 +- 0.01 for both compounds which is close to that expected for a γ6 ground state crystalline field splitting of the Nd 4f3 (J = 9/2) configuration. The hyperfine constants appropriate to 1 4 3Nd and 1 4 5Nd were found to be smaller than the free ionic values. This decrease is attributed to conduction electrons effects.

AB - We report an ESR study of Nd3+ in the cubic d band intermetallic compounds LuRh2 and LuIr2. The g value was found to be g = 2.62 +- 0.01 for both compounds which is close to that expected for a γ6 ground state crystalline field splitting of the Nd 4f3 (J = 9/2) configuration. The hyperfine constants appropriate to 1 4 3Nd and 1 4 5Nd were found to be smaller than the free ionic values. This decrease is attributed to conduction electrons effects.

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JF - Journal of Magnetism and Magnetic Materials

IS - 1-4

ER -

Observation of Nd³⁺ paramagnetic resonance in intermetallic compounds

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