On rotational and vibrational relaxation of diatomic molecules and a quasi-classical model for rotational relaxation

Tova Feldmann; A. Ben-Shaul

doi:10.1016/0009-2614(79)80514-X

On rotational and vibrational relaxation of diatomic molecules and a quasi-classical model for rotational relaxation

Tova Feldmann^*, A. Ben-Shaul

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Differences between vibrational and rotational relaxation patterns disappear and similarities are revealed by transforming from state to energy distribution. This follows from the constant state density of both oscillators and rotors and the exponential gap law governing their relaxation. A simple, parameter-free, rotational model which agrees well with previous results is formulated.

Original language	English
Pages (from-to)	286-290
Number of pages	5
Journal	Chemical Physics Letters
Volume	64
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(79)80514-X
State	Published - 1 Jul 1979

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title = "On rotational and vibrational relaxation of diatomic molecules and a quasi-classical model for rotational relaxation",

abstract = "Differences between vibrational and rotational relaxation patterns disappear and similarities are revealed by transforming from state to energy distribution. This follows from the constant state density of both oscillators and rotors and the exponential gap law governing their relaxation. A simple, parameter-free, rotational model which agrees well with previous results is formulated.",

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N2 - Differences between vibrational and rotational relaxation patterns disappear and similarities are revealed by transforming from state to energy distribution. This follows from the constant state density of both oscillators and rotors and the exponential gap law governing their relaxation. A simple, parameter-free, rotational model which agrees well with previous results is formulated.

AB - Differences between vibrational and rotational relaxation patterns disappear and similarities are revealed by transforming from state to energy distribution. This follows from the constant state density of both oscillators and rotors and the exponential gap law governing their relaxation. A simple, parameter-free, rotational model which agrees well with previous results is formulated.

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On rotational and vibrational relaxation of diatomic molecules and a quasi-classical model for rotational relaxation

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