TY - JOUR
T1 - On the difference between the thermodynamic behavior of argon in D 2O and H2O
AU - Ben-Naim, A.
PY - 1965
Y1 - 1965
N2 - The solubility of argon was measured in D2O (99.7%) at five temperatures: 5°, 10°, 15°, 20°, 25°C. The standard entropies, enthalpies, and free energies of solution were calculated, and compared with the corresponding values in H2O. The differences in the thermodynamic functions of solution in D2O and in H2O are interpreted in terms of the "two-structure" model for liquid water, and are attributed to the difference in the "degree of crystallinity" of the two solvents.
AB - The solubility of argon was measured in D2O (99.7%) at five temperatures: 5°, 10°, 15°, 20°, 25°C. The standard entropies, enthalpies, and free energies of solution were calculated, and compared with the corresponding values in H2O. The differences in the thermodynamic functions of solution in D2O and in H2O are interpreted in terms of the "two-structure" model for liquid water, and are attributed to the difference in the "degree of crystallinity" of the two solvents.
UR - http://www.scopus.com/inward/record.url?scp=0042791429&partnerID=8YFLogxK
U2 - 10.1063/1.1696153
DO - 10.1063/1.1696153
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AN - SCOPUS:0042791429
SN - 0021-9606
VL - 42
SP - 1512
EP - 1514
JO - The Journal of Chemical Physics
JF - The Journal of Chemical Physics
IS - 5
ER -