TY - JOUR
T1 - On the molar volumes and viscosities of electrolytes
AU - Marcus, Yizhak
PY - 2006/9
Y1 - 2006/9
N2 - The b V coefficient of the term linear with the concentration of the apparent molar volume φ V of electrolytes in water and several non-aqueous solvents is examined. Its relationship with the B η coefficient of the corresponding term in the relative viscosity of these electrolyte solutions is explored. Positive correlations are found in some cases as expected, but in others, where crowding of the solvation shells occurs on increasing concentration, such correlations fail.
AB - The b V coefficient of the term linear with the concentration of the apparent molar volume φ V of electrolytes in water and several non-aqueous solvents is examined. Its relationship with the B η coefficient of the corresponding term in the relative viscosity of these electrolyte solutions is explored. Positive correlations are found in some cases as expected, but in others, where crowding of the solvation shells occurs on increasing concentration, such correlations fail.
KW - Apparent molar volume
KW - Aqueous electrolytes
KW - Non-aqueous solutions
KW - Viscosity B-coefficient
UR - http://www.scopus.com/inward/record.url?scp=33750316445&partnerID=8YFLogxK
U2 - 10.1007/s10953-006-9058-5
DO - 10.1007/s10953-006-9058-5
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AN - SCOPUS:33750316445
SN - 0095-9782
VL - 35
SP - 1271
EP - 1286
JO - Journal of Solution Chemistry
JF - Journal of Solution Chemistry
IS - 9
ER -