Abstract
The anomalous partial molar heat capacity of a non-polar solute in water is discussed in terms of a two-structure model. Interpretation of the various contributions to this quantity is involved even with the simplest model for water. A simple model is designed in which the main features relevant to the problem are included. An exact solution of this model enables a detailed study of the behaviour of the heat capacity in such systems.
| Original language | English |
|---|---|
| Pages (from-to) | 2749-2760 |
| Number of pages | 12 |
| Journal | Transactions of the Faraday Society |
| Volume | 66 |
| DOIs | |
| State | Published - 1970 |